Which of the following compounds will undergo electrophilic substitution more re

Practice Questions

Q1
Which of the following compounds will undergo electrophilic substitution more readily?
  1. Benzene
  2. Toluene
  3. Chlorobenzene
  4. Nitrobenzene

Questions & Step-by-Step Solutions

Which of the following compounds will undergo electrophilic substitution more readily?
  • Step 1: Understand what electrophilic substitution is. It is a reaction where an electrophile replaces a hydrogen atom in an aromatic compound.
  • Step 2: Identify the compounds in the question. We are comparing toluene and benzene.
  • Step 3: Know the structure of toluene. Toluene has a methyl group (–CH3) attached to a benzene ring.
  • Step 4: Understand the effect of the methyl group. The methyl group is an electron-donating group, which means it increases the electron density on the benzene ring.
  • Step 5: Compare the reactivity of toluene and benzene. More electron density on the benzene ring makes it more reactive towards electrophiles.
  • Step 6: Conclude that toluene will undergo electrophilic substitution more readily than benzene because of the electron-donating effect of the methyl group.
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