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In the nitration of benzene, which reagent is used to generate the nitronium ion

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Question: In the nitration of benzene, which reagent is used to generate the nitronium ion (NO2+)?

Options:

  1. HNO3
  2. H2SO4
  3. HCl
  4. NaNO2

Correct Answer: H2SO4

Solution:

Concentrated sulfuric acid (H2SO4) is used to generate the nitronium ion (NO2+) from nitric acid (HNO3) in the nitration of benzene.

In the nitration of benzene, which reagent is used to generate the nitronium ion

Practice Questions

Q1
In the nitration of benzene, which reagent is used to generate the nitronium ion (NO2+)?
  1. HNO3
  2. H2SO4
  3. HCl
  4. NaNO2

Questions & Step-by-Step Solutions

In the nitration of benzene, which reagent is used to generate the nitronium ion (NO2+)?
  • Step 1: Understand that nitration of benzene is a chemical reaction where a nitro group (NO2) is added to benzene.
  • Step 2: Know that the nitronium ion (NO2+) is the active species that will react with benzene.
  • Step 3: Identify the reagents needed to generate the nitronium ion.
  • Step 4: Recognize that concentrated sulfuric acid (H2SO4) is used in this process.
  • Step 5: Learn that concentrated sulfuric acid reacts with nitric acid (HNO3) to produce the nitronium ion (NO2+).
  • Step 6: Conclude that the combination of concentrated sulfuric acid and nitric acid is essential for the nitration of benzene.
  • Nitration of Benzene – The process of introducing a nitro group (NO2) into the benzene ring, typically using a mixture of nitric acid and sulfuric acid.
  • Generation of Nitronium Ion – The formation of the nitronium ion (NO2+) from nitric acid in the presence of concentrated sulfuric acid, which acts as a dehydrating agent.
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