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In the presence of a strong electrophile, which aromatic compound will undergo s

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Question: In the presence of a strong electrophile, which aromatic compound will undergo substitution the fastest?

Options:

  1. Benzene
  2. Phenol
  3. Aniline
  4. Toluene

Correct Answer: Aniline

Solution:

Aniline will undergo substitution the fastest due to the strong activating effect of the amino group, which donates electron density to the ring.

In the presence of a strong electrophile, which aromatic compound will undergo s

Practice Questions

Q1
In the presence of a strong electrophile, which aromatic compound will undergo substitution the fastest?
  1. Benzene
  2. Phenol
  3. Aniline
  4. Toluene

Questions & Step-by-Step Solutions

In the presence of a strong electrophile, which aromatic compound will undergo substitution the fastest?
  • Step 1: Understand what an electrophile is. An electrophile is a chemical species that seeks to gain electrons and can react with electron-rich compounds.
  • Step 2: Know what aromatic compounds are. Aromatic compounds are a class of compounds that contain a benzene ring, which is stable and has delocalized electrons.
  • Step 3: Identify the role of substituents on the aromatic ring. Some groups can either activate or deactivate the ring towards electrophilic substitution.
  • Step 4: Recognize that the amino group (-NH2) is an activating group. It donates electron density to the benzene ring, making it more reactive towards electrophiles.
  • Step 5: Compare aniline (which has an amino group) with other aromatic compounds that have less activating or deactivating groups.
  • Step 6: Conclude that aniline will undergo substitution the fastest because the amino group significantly increases the electron density of the ring, making it more attractive to electrophiles.
  • Aromatic Substitution – The process by which an aromatic compound undergoes a reaction where an atom, typically hydrogen, is replaced by another atom or group.
  • Electrophilic Aromatic Substitution – A reaction mechanism where an electrophile reacts with an aromatic compound, leading to substitution on the aromatic ring.
  • Activating and Deactivating Groups – Groups attached to the aromatic ring that either increase (activating) or decrease (deactivating) the rate of electrophilic substitution.
  • Electron Donating Groups – Groups that donate electron density to the aromatic ring, enhancing its reactivity towards electrophiles.
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