What is the relationship between the equilibrium constant (K) and the Gibbs free

Practice Questions

Q1
What is the relationship between the equilibrium constant (K) and the Gibbs free energy change (ΔG) for a reaction?
  1. ΔG = -RT ln(K)
  2. ΔG = RT ln(K)
  3. ΔG = KRT
  4. ΔG = K/R

Questions & Step-by-Step Solutions

What is the relationship between the equilibrium constant (K) and the Gibbs free energy change (ΔG) for a reaction?
  • Step 1: Understand that K is the equilibrium constant, which tells us the ratio of products to reactants at equilibrium.
  • Step 2: Know that ΔG is the change in Gibbs free energy, which indicates whether a reaction is spontaneous or not.
  • Step 3: Learn the equation that connects K and ΔG: ΔG = -RT ln(K).
  • Step 4: Identify R as the gas constant, which is approximately 8.314 J/(mol·K).
  • Step 5: Recognize that T is the temperature in Kelvin, which is important for the calculation.
  • Step 6: Realize that if K is greater than 1, ΔG is negative, meaning the reaction is spontaneous in the forward direction.
  • Step 7: Conversely, if K is less than 1, ΔG is positive, indicating the reaction is not spontaneous in the forward direction.
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