What type of reaction occurs when haloalkanes react with alcoholic KOH?

Practice Questions

Q1
What type of reaction occurs when haloalkanes react with alcoholic KOH?
  1. Nucleophilic substitution
  2. Elimination
  3. Addition
  4. Redox

Questions & Step-by-Step Solutions

What type of reaction occurs when haloalkanes react with alcoholic KOH?
Correct Answer: Nucleophilic substitution
  • Step 1: Understand what haloalkanes are. They are organic compounds that contain carbon, hydrogen, and halogen atoms (like chlorine, bromine, or iodine).
  • Step 2: Know what alcoholic KOH is. It is potassium hydroxide dissolved in alcohol, which acts as a strong base.
  • Step 3: Recognize that in this reaction, the KOH acts as a nucleophile. A nucleophile is a species that donates an electron pair to form a chemical bond.
  • Step 4: Identify the type of reaction. When haloalkanes react with alcoholic KOH, the halogen atom is replaced by a hydroxyl group (-OH) from the KOH.
  • Step 5: Conclude that this process is called nucleophilic substitution because the nucleophile (KOH) substitutes the halogen in the haloalkane.
  • Step 6: The final product of this reaction is an alcohol, which is a compound that contains one or more hydroxyl (-OH) groups.
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