What is the product of the reaction between an aldehyde and a Grignard reagent?

Practice Questions

Q1
What is the product of the reaction between an aldehyde and a Grignard reagent?
  1. Alcohol
  2. Ketone
  3. Carboxylic acid
  4. Alkane

Questions & Step-by-Step Solutions

What is the product of the reaction between an aldehyde and a Grignard reagent?
Correct Answer: Secondary alcohol
  • Step 1: Identify the aldehyde and the Grignard reagent. An aldehyde has the structure RCHO, where R is a hydrocarbon group.
  • Step 2: The Grignard reagent has the structure RMgX, where R is a hydrocarbon group and X is a halogen (like Cl, Br, or I).
  • Step 3: When the Grignard reagent is added to the aldehyde, it reacts with the carbonyl carbon (C=O) of the aldehyde.
  • Step 4: This reaction forms a new carbon-carbon bond, resulting in an intermediate compound called an alkoxide.
  • Step 5: The alkoxide is then treated with water (hydrolysis), which converts it into a secondary alcohol.
  • Step 6: The final product is a secondary alcohol, which has the structure R2CHOH, where R is the hydrocarbon group from the aldehyde and the Grignard reagent.
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