Step 1: Identify the central atom in SF6, which is sulfur (S).
Step 2: Count the number of fluorine (F) atoms bonded to sulfur. There are 6 fluorine atoms.
Step 3: Determine the number of bonding pairs. Each fluorine atom forms one bond with sulfur, resulting in 6 bonding pairs.
Step 4: Check for lone pairs on the central atom (sulfur). In SF6, there are no lone pairs on sulfur.
Step 5: Use the number of bonding pairs and lone pairs to determine the electron pair geometry. With 6 bonding pairs and 0 lone pairs, the geometry is octahedral.