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What is the hybridization of the phosphorus atom in PCl5?

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Question: What is the hybridization of the phosphorus atom in PCl5?

Options:

  1. sp
  2. sp2
  3. sp3
  4. d2sp3

Correct Answer: d2sp3

Solution: 

In PCl5, phosphorus is surrounded by five chlorine atoms, indicating d2sp3 hybridization.

What is the hybridization of the phosphorus atom in PCl5?

Practice Questions

Q1
What is the hybridization of the phosphorus atom in PCl5?
  1. sp
  2. sp2
  3. sp3
  4. d2sp3

Questions & Step-by-Step Solutions

What is the hybridization of the phosphorus atom in PCl5?
Correct Answer: d2sp3
  • Step 1: Identify the central atom in PCl5, which is phosphorus (P).
  • Step 2: Count the number of chlorine (Cl) atoms bonded to phosphorus. There are 5 Cl atoms.
  • Step 3: Determine the number of electron pairs around phosphorus. Each Cl atom forms one bond, so there are 5 bonding pairs.
  • Step 4: Recognize that phosphorus can use its d orbitals for hybridization because it is in the third period of the periodic table.
  • Step 5: Combine the bonding pairs with the available orbitals: 1 s orbital, 3 p orbitals, and 2 d orbitals (d2sp3).
  • Step 6: Conclude that the hybridization of phosphorus in PCl5 is d2sp3.
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