Which of the following is the correct order of basicity for the given amines?
Practice Questions
Q1
Which of the following is the correct order of basicity for the given amines?
RNH2 > R2NH > R3N
R3N > R2NH > RNH2
R2NH > R3N > RNH2
RNH2 > R3N > R2NH
Questions & Step-by-Step Solutions
Which of the following is the correct order of basicity for the given amines?
Correct Answer: Tertiary > Secondary > Primary
Step 1: Understand that basicity refers to how well a substance can accept protons (H+).
Step 2: Recognize that amines are compounds that contain nitrogen and can act as bases.
Step 3: Identify the types of amines: primary (1 alkyl group), secondary (2 alkyl groups), and tertiary (3 alkyl groups).
Step 4: Know that as the number of alkyl groups increases, steric hindrance (crowding around the nitrogen) increases.
Step 5: Realize that more alkyl groups also mean more electron-donating effects, which can stabilize the positive charge when the amine accepts a proton.
Step 6: Conclude that the basicity decreases with more alkyl substitution due to the combined effects of steric hindrance and electron donation.