What type of isomerism is shown by [Co(en)3]3+?

Practice Questions

Q1
What type of isomerism is shown by [Co(en)3]3+?
  1. Geometrical
  2. Optical
  3. Structural
  4. Linkage

Questions & Step-by-Step Solutions

What type of isomerism is shown by [Co(en)3]3+?
Correct Answer: Optical Isomerism
  • Step 1: Identify the complex ion [Co(en)3]3+. This means it has a cobalt (Co) ion and three ethylenediamine (en) ligands.
  • Step 2: Understand what a bidentate ligand is. A bidentate ligand can attach to a metal ion at two points. Ethylenediamine (en) is a bidentate ligand.
  • Step 3: Determine the structure of [Co(en)3]3+. The three en ligands wrap around the cobalt ion in a way that can create different spatial arrangements.
  • Step 4: Recognize that chiral centers are points in a molecule where the arrangement of atoms can lead to non-superimposable mirror images (like left and right hands).
  • Step 5: Conclude that since [Co(en)3]3+ has chiral centers due to the arrangement of the bidentate ligands, it can exist in two forms that are mirror images of each other.
  • Step 6: Therefore, [Co(en)3]3+ exhibits optical isomerism.
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