Which of the following alcohols is most acidic?

Practice Questions

Q1
Which of the following alcohols is most acidic?
  1. Methanol
  2. Ethanol
  3. Isopropanol
  4. Tert-butanol

Questions & Step-by-Step Solutions

Which of the following alcohols is most acidic?
Correct Answer: Methanol
  • Step 1: Understand what acidity means in the context of alcohols. Acidity refers to how easily an alcohol can donate a proton (H+).
  • Step 2: Identify the alcohols being compared. Common alcohols include methanol, ethanol, and others.
  • Step 3: Recognize that steric hindrance refers to the crowding around a reactive site, which can affect how easily a proton can be donated.
  • Step 4: Compare the structures of the alcohols. Methanol (CH3OH) has a simple structure with no bulky groups around the hydroxyl (-OH) group.
  • Step 5: Note that alcohols with more bulky groups (like tert-butanol) have more steric hindrance, making it harder for them to donate a proton.
  • Step 6: Conclude that methanol, having no steric hindrance, can donate a proton more easily than the other alcohols, making it the most acidic.
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