For the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of de

Practice Questions

Q1
For the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of decreasing the volume of the container? (2021)
  1. Shift to the left
  2. Shift to the right
  3. No effect
  4. Increase in temperature

Questions & Step-by-Step Solutions

For the equilibrium reaction 2SO2(g) + O2(g) ⇌ 2SO3(g), what is the effect of decreasing the volume of the container? (2021)
  • Step 1: Understand the reaction: 2SO2(g) + O2(g) ⇌ 2SO3(g). This means that two molecules of sulfur dioxide (SO2) and one molecule of oxygen (O2) can turn into two molecules of sulfur trioxide (SO3).
  • Step 2: Recognize that the left side (reactants) has 3 gas molecules (2 SO2 + 1 O2) and the right side (products) has 2 gas molecules (2 SO3).
  • Step 3: Know that decreasing the volume of the container increases the pressure inside the container.
  • Step 4: Apply Le Chatelier's principle, which states that if a system at equilibrium is disturbed, it will shift to counteract the disturbance.
  • Step 5: Since the pressure increases when the volume decreases, the equilibrium will shift towards the side with fewer gas molecules to reduce the pressure.
  • Step 6: In this reaction, the right side has fewer gas molecules (2 SO3) compared to the left side (3 total gas molecules). Therefore, the equilibrium will shift to the right.
  • Le Chatelier's Principle – This principle states that if an external change is applied to a system at equilibrium, the system will adjust to counteract that change and restore a new equilibrium.
  • Gas Laws – Understanding how changes in volume affect pressure and the behavior of gases in a closed system.
  • Stoichiometry of Gases – Recognizing the relationship between the number of moles of reactants and products in a chemical reaction.
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