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What type of isomerism is shown by the complex [Co(en)2Cl2]+? (2021)

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Question: What type of isomerism is shown by the complex [Co(en)2Cl2]+? (2021)

Options:

  1. Geometrical
  2. Optical
  3. Structural
  4. Coordination

Correct Answer: Optical

Exam Year: 2021

Solution: 

The complex [Co(en)2Cl2]+ can exhibit optical isomerism due to the presence of bidentate ligands (en = ethylenediamine) which can create non-superimposable mirror images.

What type of isomerism is shown by the complex [Co(en)2Cl2]+? (2021)

Practice Questions

Q1
What type of isomerism is shown by the complex [Co(en)2Cl2]+? (2021)
  1. Geometrical
  2. Optical
  3. Structural
  4. Coordination

Questions & Step-by-Step Solutions

What type of isomerism is shown by the complex [Co(en)2Cl2]+? (2021)
  • Step 1: Identify the complex. The complex is [Co(en)2Cl2]+.
  • Step 2: Recognize the ligands. The ligands are 'en' (ethylenediamine) which is a bidentate ligand, and 'Cl' (chloride) which is a monodentate ligand.
  • Step 3: Understand what bidentate means. Bidentate ligands can attach to the metal at two points, creating a more complex structure.
  • Step 4: Determine the geometry of the complex. The presence of two bidentate ligands can lead to a specific 3D shape.
  • Step 5: Learn about optical isomerism. Optical isomerism occurs when a molecule can exist in two forms that are mirror images of each other and cannot be superimposed.
  • Step 6: Conclude that the complex can exhibit optical isomerism because the arrangement of the bidentate ligands allows for non-superimposable mirror images.
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