What is the hybridization of the central metal ion in [Cr(NH3)6]3+? (2020) 2020

Practice Questions

Q1
What is the hybridization of the central metal ion in [Cr(NH3)6]3+? (2020) 2020
  1. sp
  2. sp2
  3. d2sp3
  4. dsp2

Questions & Step-by-Step Solutions

What is the hybridization of the central metal ion in [Cr(NH3)6]3+? (2020) 2020
  • Step 1: Identify the central metal ion in the complex [Cr(NH3)6]3+. The central metal ion is chromium (Cr).
  • Step 2: Determine the oxidation state of chromium in the complex. Since the overall charge is +3 and ammonia (NH3) is a neutral ligand, the oxidation state of Cr is +3.
  • Step 3: Write the electron configuration of chromium in its elemental form. Chromium (Cr) has an atomic number of 24, so its electron configuration is [Ar] 3d5 4s1.
  • Step 4: Adjust the electron configuration for the +3 oxidation state. Remove 3 electrons (2 from 4s and 1 from 3d), resulting in [Ar] 3d3.
  • Step 5: Determine the coordination number. In [Cr(NH3)6]3+, there are six ammonia ligands coordinating to the chromium ion, giving a coordination number of 6.
  • Step 6: Identify the geometry based on the coordination number. A coordination number of 6 typically results in an octahedral geometry.
  • Step 7: Determine the hybridization based on the octahedral geometry. For octahedral complexes, the hybridization is d2sp3.
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