In which of the following scenarios is ΔG equal to ΔH?

Practice Questions

Q1
In which of the following scenarios is ΔG equal to ΔH?
  1. At high temperatures with ΔS = 0.
  2. At low temperatures with ΔS = 0.
  3. At constant pressure and temperature.
  4. In a phase transition.

Questions & Step-by-Step Solutions

In which of the following scenarios is ΔG equal to ΔH?
  • Step 1: Understand what ΔG and ΔH represent. ΔG is the change in Gibbs free energy, and ΔH is the change in enthalpy (heat content).
  • Step 2: Know that ΔG indicates whether a process is spontaneous (can happen on its own) or not.
  • Step 3: Recognize that during a phase transition (like melting ice to water or boiling water to steam), the system is at equilibrium.
  • Step 4: At equilibrium, the energy changes in the system balance out, which means ΔG equals ΔH.
  • Step 5: Conclude that ΔG equals ΔH specifically during phase transitions because the system is not gaining or losing energy in a way that drives it away from equilibrium.
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