What is the reduction half-reaction for the reaction of MnO4- in acidic medium?

Practice Questions

Q1
What is the reduction half-reaction for the reaction of MnO4- in acidic medium?
  1. MnO4- + 8H+ + 5e- → Mn2+ + 4H2O
  2. MnO4- + 3e- → MnO2 + 2H2O
  3. MnO4- + 2e- → MnO2 + 4H+
  4. MnO4- + 4e- + 8H+ → MnO2 + 4H2O

Questions & Step-by-Step Solutions

What is the reduction half-reaction for the reaction of MnO4- in acidic medium?
  • Step 1: Identify the species being reduced. In this case, it is MnO4- (permanganate ion).
  • Step 2: Determine the oxidation state of manganese in MnO4-. It is +7.
  • Step 3: Identify the product of the reduction. In acidic medium, MnO4- is reduced to Mn2+.
  • Step 4: Write the half-reaction for the reduction. Start with MnO4- and show it gaining electrons to become Mn2+.
  • Step 5: Balance the charge by adding electrons. Since MnO4- has a charge of -1 and Mn2+ has a charge of +2, you need to add 8 electrons to the left side: MnO4- + 8e- → Mn2+.
  • Step 6: Balance the oxygen atoms by adding water molecules. There are 4 oxygen atoms in MnO4-, so add 4 H2O to the right side: MnO4- + 8e- → Mn2+ + 4H2O.
  • Step 7: Balance the hydrogen atoms by adding H+ ions. There are 8 hydrogen atoms in 4 H2O, so add 8 H+ to the left side: MnO4- + 8e- + 8H+ → Mn2+ + 4H2O.
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