How does the presence of a -I group affect the stability of a carbocation?

Practice Questions

Q1
How does the presence of a -I group affect the stability of a carbocation?
  1. Increases stability
  2. Decreases stability
  3. No effect
  4. Depends on the size of the group

Questions & Step-by-Step Solutions

How does the presence of a -I group affect the stability of a carbocation?
  • Step 1: Understand what a carbocation is. A carbocation is a positively charged carbon atom that has only three bonds instead of four.
  • Step 2: Learn about -I groups. A -I group (electron-withdrawing group) pulls electrons away from the carbon atom.
  • Step 3: Recognize that carbocations need electron density to be stable. They are positively charged and want more electrons to balance that charge.
  • Step 4: Realize that when a -I group is present, it takes away electron density from the carbocation.
  • Step 5: Conclude that because the -I group withdraws electrons, it makes the carbocation less stable.
  • Inductive Effect – The -I (negative inductive) effect refers to the electron-withdrawing nature of certain groups, which decreases electron density in nearby atoms or groups.
  • Carbocation Stability – Carbocation stability is influenced by the electron-donating or withdrawing effects of substituents; more electron density generally stabilizes carbocations.
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