How does the presence of a -I group affect the stability of a carbocation?
Practice Questions
Q1
How does the presence of a -I group affect the stability of a carbocation?
Increases stability
Decreases stability
No effect
Depends on the size of the group
Questions & Step-by-Step Solutions
How does the presence of a -I group affect the stability of a carbocation?
Step 1: Understand what a carbocation is. A carbocation is a positively charged carbon atom that has only three bonds instead of four.
Step 2: Learn about -I groups. A -I group (electron-withdrawing group) pulls electrons away from the carbon atom.
Step 3: Recognize that carbocations need electron density to be stable. They are positively charged and want more electrons to balance that charge.
Step 4: Realize that when a -I group is present, it takes away electron density from the carbocation.
Step 5: Conclude that because the -I group withdraws electrons, it makes the carbocation less stable.
Inductive Effect – The -I (negative inductive) effect refers to the electron-withdrawing nature of certain groups, which decreases electron density in nearby atoms or groups.
Carbocation Stability – Carbocation stability is influenced by the electron-donating or withdrawing effects of substituents; more electron density generally stabilizes carbocations.