What is the hybridization of the central atom in [Ni(CN)4]2-?

Practice Questions

Q1
What is the hybridization of the central atom in [Ni(CN)4]2-?
  1. sp
  2. sp2
  3. sp3
  4. dsp2

Questions & Step-by-Step Solutions

What is the hybridization of the central atom in [Ni(CN)4]2-?
  • Step 1: Identify the central atom in the complex [Ni(CN)4]2-. The central atom is nickel (Ni).
  • Step 2: Determine the oxidation state of nickel in the complex. Since the overall charge is -2 and each cyanide (CN) ligand has a charge of -1, nickel must be in the +2 oxidation state.
  • Step 3: Count the number of ligands attached to the central atom. There are four cyanide ligands (CN) attached to nickel.
  • Step 4: Determine the type of hybridization needed for nickel to bond with the four ligands. Since there are four ligands, we need to use dsp2 hybridization.
  • Step 5: Conclude that the hybridization of the central atom nickel in [Ni(CN)4]2- is dsp2.
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