If a reaction has ΔH = 100 kJ and ΔS = -200 J/K, what is ΔG at 298 K?

Practice Questions

Q1
If a reaction has ΔH = 100 kJ and ΔS = -200 J/K, what is ΔG at 298 K?
  1. 0 kJ
  2. 100 kJ
  3. 200 kJ
  4. 300 kJ

Questions & Step-by-Step Solutions

If a reaction has ΔH = 100 kJ and ΔS = -200 J/K, what is ΔG at 298 K?
  • Step 1: Identify the values given in the problem. We have ΔH = 100 kJ and ΔS = -200 J/K.
  • Step 2: Convert ΔS from J/K to kJ/K because ΔH is in kJ. Since 1 kJ = 1000 J, we convert -200 J/K to kJ/K: -200 J/K = -0.2 kJ/K.
  • Step 3: Identify the temperature (T) given in the problem, which is 298 K.
  • Step 4: Use the formula for Gibbs free energy: ΔG = ΔH - TΔS.
  • Step 5: Substitute the values into the formula: ΔG = 100 kJ - 298 K * (-0.2 kJ/K).
  • Step 6: Calculate TΔS: 298 K * (-0.2 kJ/K) = -59.6 kJ.
  • Step 7: Now substitute this value back into the equation: ΔG = 100 kJ + 59.6 kJ.
  • Step 8: Finally, calculate ΔG: ΔG = 159.6 kJ.
  • Gibbs Free Energy – The relationship between enthalpy (ΔH), entropy (ΔS), and temperature (T) to determine the spontaneity of a reaction using the equation ΔG = ΔH - TΔS.
  • Unit Conversion – Understanding the need to convert units, particularly ensuring that ΔS is in kJ/K when calculating ΔG in kJ.
  • Temperature Dependence – Recognizing how temperature affects the Gibbs free energy calculation and the significance of using the correct temperature in Kelvin.
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