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In a binary solution of A and B, if component A has a higher vapor pressure than

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Question: In a binary solution of A and B, if component A has a higher vapor pressure than component B, what can be inferred about the solution?

Options:

  1. It will show positive deviation from Raoult\'s Law.
  2. It will show negative deviation from Raoult\'s Law.
  3. It will have a lower boiling point than pure A.
  4. It will have a higher boiling point than pure B.

Correct Answer: It will show positive deviation from Raoult\'s Law.

Solution:

If component A has a higher vapor pressure than component B, the solution will show positive deviation from Raoult\'s Law.

In a binary solution of A and B, if component A has a higher vapor pressure than

Practice Questions

Q1
In a binary solution of A and B, if component A has a higher vapor pressure than component B, what can be inferred about the solution?
  1. It will show positive deviation from Raoult's Law.
  2. It will show negative deviation from Raoult's Law.
  3. It will have a lower boiling point than pure A.
  4. It will have a higher boiling point than pure B.

Questions & Step-by-Step Solutions

In a binary solution of A and B, if component A has a higher vapor pressure than component B, what can be inferred about the solution?
  • Step 1: Understand what vapor pressure means. Vapor pressure is the pressure exerted by a vapor in equilibrium with its liquid or solid phase.
  • Step 2: Recognize that in a binary solution, we have two components: A and B.
  • Step 3: Note that if component A has a higher vapor pressure than component B, it means A evaporates more easily than B.
  • Step 4: Recall Raoult's Law, which states that the vapor pressure of a component in a solution is proportional to its mole fraction in the solution.
  • Step 5: Understand that a positive deviation from Raoult's Law occurs when the vapor pressure of the solution is higher than expected based on the individual vapor pressures of A and B.
  • Step 6: Conclude that since A has a higher vapor pressure, the solution will exhibit a positive deviation from Raoult's Law.
  • Vapor Pressure and Raoult's Law – The relationship between the vapor pressures of components in a solution and how they deviate from ideal behavior as described by Raoult's Law.
  • Positive Deviation from Raoult's Law – Occurs when the vapor pressure of a solution is higher than predicted by Raoult's Law, indicating weaker interactions between different components.
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