Which of the following compounds is not an aromatic hydrocarbon?

Practice Questions

Q1
Which of the following compounds is not an aromatic hydrocarbon?
  1. Naphthalene
  2. Benzene
  3. Cyclooctatetraene
  4. Anthracene

Questions & Step-by-Step Solutions

Which of the following compounds is not an aromatic hydrocarbon?
  • Step 1: Understand what an aromatic hydrocarbon is. Aromatic hydrocarbons are compounds that have a ring structure, are cyclic, and follow Huckel's rule.
  • Step 2: Recall Huckel's rule, which states that a compound is aromatic if it has (4n + 2) π electrons, where n is a non-negative integer.
  • Step 3: Identify the compounds in the question. One of them is Cyclooctatetraene.
  • Step 4: Check the structure of Cyclooctatetraene. It has 8 π electrons, which does not fit Huckel's rule (it should have 6, 10, 14, etc. π electrons).
  • Step 5: Determine if Cyclooctatetraene is planar. Aromatic compounds must be planar to allow for delocalization of electrons. Cyclooctatetraene is not planar.
  • Step 6: Conclude that Cyclooctatetraene is not an aromatic hydrocarbon because it does not satisfy Huckel's rule and is not planar.
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