Which of the following conditions will lead to a spontaneous reaction?

Practice Questions

Q1
Which of the following conditions will lead to a spontaneous reaction?
  1. ΔH > 0 and ΔS < 0
  2. ΔH < 0 and ΔS > 0
  3. ΔH > 0 and ΔS > 0
  4. ΔH < 0 and ΔS < 0

Questions & Step-by-Step Solutions

Which of the following conditions will lead to a spontaneous reaction?
  • Step 1: Understand that a spontaneous reaction is one that occurs naturally without needing extra energy.
  • Step 2: Learn about ΔG, which is the change in Gibbs free energy. A spontaneous reaction happens when ΔG is less than 0 (ΔG < 0).
  • Step 3: Know that ΔG can be calculated using the formula: ΔG = ΔH - TΔS, where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
  • Step 4: Recognize that if ΔH (enthalpy change) is less than 0 (ΔH < 0), it means the reaction releases heat, which is favorable for spontaneity.
  • Step 5: Understand that if ΔS (entropy change) is greater than 0 (ΔS > 0), it means the disorder of the system increases, which is also favorable for spontaneity.
  • Step 6: Conclude that both conditions (ΔH < 0 and ΔS > 0) together will lead to a negative ΔG, resulting in a spontaneous reaction.
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