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Which of the following reactions will have a negative ΔG at high temperatures?
Practice Questions
Q1
Which of the following reactions will have a negative ΔG at high temperatures?
Exothermic reactions with negative ΔS
Endothermic reactions with positive ΔS
Exothermic reactions with positive ΔS
Endothermic reactions with negative ΔS
Questions & Step-by-Step Solutions
Which of the following reactions will have a negative ΔG at high temperatures?
Steps
Concepts
Step 1: Understand what ΔG means. ΔG is the change in free energy of a reaction. A negative ΔG means the reaction is spontaneous.
Step 2: Know the formula for ΔG: ΔG = ΔH - TΔS, where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
Step 3: Identify what endothermic means. An endothermic reaction has a positive ΔH, meaning it absorbs heat.
Step 4: Recognize that ΔS can be positive or negative. A positive ΔS means the disorder of the system increases.
Step 5: At high temperatures, the TΔS term becomes larger. If ΔS is positive, TΔS will also be positive and can outweigh the positive ΔH.
Step 6: Conclude that if a reaction is endothermic (positive ΔH) and has a positive ΔS, then at high temperatures, TΔS can make ΔG negative.
No concepts available.
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