Which of the following reactions will have a negative ΔG at high temperatures?

Practice Questions

Q1
Which of the following reactions will have a negative ΔG at high temperatures?
  1. Exothermic reactions with negative ΔS
  2. Endothermic reactions with positive ΔS
  3. Exothermic reactions with positive ΔS
  4. Endothermic reactions with negative ΔS

Questions & Step-by-Step Solutions

Which of the following reactions will have a negative ΔG at high temperatures?
  • Step 1: Understand what ΔG means. ΔG is the change in free energy of a reaction. A negative ΔG means the reaction is spontaneous.
  • Step 2: Know the formula for ΔG: ΔG = ΔH - TΔS, where ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
  • Step 3: Identify what endothermic means. An endothermic reaction has a positive ΔH, meaning it absorbs heat.
  • Step 4: Recognize that ΔS can be positive or negative. A positive ΔS means the disorder of the system increases.
  • Step 5: At high temperatures, the TΔS term becomes larger. If ΔS is positive, TΔS will also be positive and can outweigh the positive ΔH.
  • Step 6: Conclude that if a reaction is endothermic (positive ΔH) and has a positive ΔS, then at high temperatures, TΔS can make ΔG negative.
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