At what temperature does a reaction become spontaneous if ΔH = 50 kJ and ΔS = 0.

Practice Questions

Q1
At what temperature does a reaction become spontaneous if ΔH = 50 kJ and ΔS = 0.1 kJ/K?
  1. 500 K
  2. 250 K
  3. 1000 K
  4. 200 K

Questions & Step-by-Step Solutions

At what temperature does a reaction become spontaneous if ΔH = 50 kJ and ΔS = 0.1 kJ/K?
  • Step 1: Understand the equation for spontaneity: ΔG = ΔH - TΔS.
  • Step 2: Recognize that a reaction becomes spontaneous when ΔG = 0.
  • Step 3: Set ΔG to 0 in the equation: 0 = ΔH - TΔS.
  • Step 4: Rearrange the equation to solve for T: T = ΔH / ΔS.
  • Step 5: Substitute the given values into the equation: T = 50 kJ / 0.1 kJ/K.
  • Step 6: Perform the division: 50 kJ divided by 0.1 kJ/K equals 500 K.
  • Step 7: Conclude that the temperature at which the reaction becomes spontaneous is 500 K.
  • Gibbs Free Energy – The relationship between enthalpy (ΔH), entropy (ΔS), and temperature (T) in determining the spontaneity of a reaction through the Gibbs free energy equation (ΔG = ΔH - TΔS).
  • Spontaneity of Reactions – Understanding that a reaction is spontaneous when ΔG is negative, which can be determined by the values of ΔH and ΔS.
  • Temperature Dependence – Recognizing how temperature influences the spontaneity of a reaction based on the signs and magnitudes of ΔH and ΔS.
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