What is the pH of a buffer solution containing 0.2 M acetic acid and 0.1 M sodiu

Practice Questions

Q1
What is the pH of a buffer solution containing 0.2 M acetic acid and 0.1 M sodium acetate?
  1. 4.76
  2. 5.00
  3. 5.74
  4. 6.00

Questions & Step-by-Step Solutions

What is the pH of a buffer solution containing 0.2 M acetic acid and 0.1 M sodium acetate?
  • Step 1: Identify the components of the buffer solution. We have acetic acid (HA) and sodium acetate (A-).
  • Step 2: Determine the concentrations of the components. We have 0.2 M acetic acid and 0.1 M sodium acetate.
  • Step 3: Find the pKa of acetic acid. The pKa is approximately 4.76.
  • Step 4: Use the Henderson-Hasselbalch equation: pH = pKa + log([A-]/[HA]).
  • Step 5: Substitute the values into the equation: pH = 4.76 + log(0.1/0.2).
  • Step 6: Calculate the ratio: 0.1/0.2 = 0.5.
  • Step 7: Find the logarithm of 0.5: log(0.5) is approximately -0.301.
  • Step 8: Add this value to the pKa: pH = 4.76 - 0.301.
  • Step 9: Calculate the final pH: pH = 4.76 - 0.301 = 4.459.
  • Step 10: Round the final answer if necessary, but in this case, we keep it as 4.459.
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