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In a closed system at equilibrium, if the volume is decreased, what will happen

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Question: In a closed system at equilibrium, if the volume is decreased, what will happen to the equilibrium position?

Options:

  1. Shift to the side with more moles of gas
  2. Shift to the side with fewer moles of gas
  3. No change
  4. Increase in pressure

Correct Answer: Shift to the side with fewer moles of gas

Solution:

Decreasing the volume increases the pressure, and the equilibrium will shift to the side with fewer moles of gas to counteract the change.

In a closed system at equilibrium, if the volume is decreased, what will happen

Practice Questions

Q1
In a closed system at equilibrium, if the volume is decreased, what will happen to the equilibrium position?
  1. Shift to the side with more moles of gas
  2. Shift to the side with fewer moles of gas
  3. No change
  4. Increase in pressure

Questions & Step-by-Step Solutions

In a closed system at equilibrium, if the volume is decreased, what will happen to the equilibrium position?
  • Step 1: Understand that a closed system means no substances can enter or leave.
  • Step 2: Recognize that equilibrium is a state where the forward and reverse reactions occur at the same rate.
  • Step 3: Know that decreasing the volume of the system will increase the pressure inside the system.
  • Step 4: Remember that according to Le Chatelier's principle, if a change is made to a system at equilibrium, the system will adjust to counteract that change.
  • Step 5: Since the pressure increases when the volume decreases, the equilibrium will shift to reduce the pressure.
  • Step 6: The side of the reaction with fewer moles of gas will help reduce the pressure, so the equilibrium will shift towards that side.
  • Le Chatelier's Principle – When a system at equilibrium is subjected to a change in conditions (such as volume or pressure), the equilibrium will shift in a direction that counteracts that change.
  • Gas Laws – Understanding the relationship between volume, pressure, and the number of moles of gas in a closed system.
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