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For the reaction 2NO(g) + O2(g) β‡Œ 2NO2(g), if the initial concentrations are [NO

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Question: For the reaction 2NO(g) + O2(g) β‡Œ 2NO2(g), if the initial concentrations are [NO]=0.5 M and [O2]=0.5 M, what will be the equilibrium concentration of NO2 if Kc=4?

Options:

  1. 0.1 M
  2. 0.2 M
  3. 0.3 M
  4. 0.4 M

Correct Answer: 0.2 M

Solution:

Using ICE table and Kc expression, we find [NO2] at equilibrium to be 0.2 M.

For the reaction 2NO(g) + O2(g) β‡Œ 2NO2(g), if the initial concentrations are [NO

Practice Questions

Q1
For the reaction 2NO(g) + O2(g) β‡Œ 2NO2(g), if the initial concentrations are [NO]=0.5 M and [O2]=0.5 M, what will be the equilibrium concentration of NO2 if Kc=4?
  1. 0.1 M
  2. 0.2 M
  3. 0.3 M
  4. 0.4 M

Questions & Step-by-Step Solutions

For the reaction 2NO(g) + O2(g) β‡Œ 2NO2(g), if the initial concentrations are [NO]=0.5 M and [O2]=0.5 M, what will be the equilibrium concentration of NO2 if Kc=4?
  • Step 1: Write down the balanced chemical equation: 2NO(g) + O2(g) β‡Œ 2NO2(g).
  • Step 2: Identify the initial concentrations: [NO] = 0.5 M and [O2] = 0.5 M.
  • Step 3: Set up an ICE table (Initial, Change, Equilibrium) for the concentrations of NO, O2, and NO2.
  • Step 4: Fill in the initial concentrations in the ICE table: NO = 0.5 M, O2 = 0.5 M, NO2 = 0 M.
  • Step 5: Let 'x' be the change in concentration of NO2 at equilibrium. Since 2 moles of NO produce 2 moles of NO2, the change for NO will be -x and for O2 will be -0.5x.
  • Step 6: Write the equilibrium concentrations in terms of 'x': [NO] = 0.5 - x, [O2] = 0.5 - 0.5x, [NO2] = 0 + x.
  • Step 7: Write the expression for Kc: Kc = [NO2]^2 / ([NO]^2 * [O2]).
  • Step 8: Substitute the equilibrium concentrations into the Kc expression: 4 = (x^2) / ((0.5 - x)^2 * (0.5 - 0.5x)).
  • Step 9: Solve the equation for 'x'. After simplification, you will find that x = 0.2.
  • Step 10: Find the equilibrium concentration of NO2: [NO2] = x = 0.2 M.
  • Equilibrium Constant (Kc) – Understanding how to use the equilibrium constant to find concentrations at equilibrium.
  • ICE Table – Using the Initial, Change, Equilibrium (ICE) table method to track concentration changes during the reaction.
  • Stoichiometry – Applying stoichiometric coefficients from the balanced equation to relate the concentrations of reactants and products.
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