Which substituent is a strong +I and +M director?

Practice Questions

Q1
Which substituent is a strong +I and +M director?
  1. -NO2
  2. -OH
  3. -CN
  4. -COOH

Questions & Step-by-Step Solutions

Which substituent is a strong +I and +M director?
  • Step 1: Understand what +I and +M directors are. +I (inductive effect) means the substituent donates electron density through sigma bonds, while +M (mesomeric effect) means it donates electron density through resonance.
  • Step 2: Identify the substituent in the question, which is -OH (hydroxyl group).
  • Step 3: Recognize that -OH has lone pairs of electrons that can be shared with the aromatic ring, allowing it to donate electron density through resonance (+M effect).
  • Step 4: Note that -OH also has an electronegative oxygen atom that can pull electron density through sigma bonds, making it a strong +I director as well.
  • Step 5: Conclude that -OH is a strong +I and +M director because it effectively donates electron density both through resonance and inductive effects.
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