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In the complex [Ni(CO)4], what is the hybridization of the nickel atom?

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Question: In the complex [Ni(CO)4], what is the hybridization of the nickel atom?

Options:

  1. sp
  2. sp2
  3. sp3
  4. d2sp3

Correct Answer: sp3

Solution:

Nickel in [Ni(CO)4] undergoes sp3 hybridization as it forms four sigma bonds with CO ligands.

In the complex [Ni(CO)4], what is the hybridization of the nickel atom?

Practice Questions

Q1
In the complex [Ni(CO)4], what is the hybridization of the nickel atom?
  1. sp
  2. sp2
  3. sp3
  4. d2sp3

Questions & Step-by-Step Solutions

In the complex [Ni(CO)4], what is the hybridization of the nickel atom?
  • Step 1: Identify the central atom in the complex [Ni(CO)4]. The central atom is nickel (Ni).
  • Step 2: Count the number of ligands attached to the nickel atom. In [Ni(CO)4], there are four CO ligands.
  • Step 3: Determine the type of bonds formed. Each CO ligand forms a sigma bond with the nickel atom.
  • Step 4: Since there are four sigma bonds, we need to find the hybridization that corresponds to four bonding regions.
  • Step 5: The hybridization that corresponds to four bonding regions is sp3 hybridization.
  • Step 6: Conclude that the hybridization of the nickel atom in [Ni(CO)4] is sp3.
  • Hybridization – The process of mixing atomic orbitals to form new hybrid orbitals suitable for the pairing of electrons to form chemical bonds.
  • Coordination Complexes – Compounds formed from a central metal atom or ion bonded to surrounding molecules or anions, known as ligands.
  • Ligand Types – CO is a neutral ligand that donates a pair of electrons to the metal center, influencing the hybridization and geometry of the complex.
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