What is the hybridization of the central atom in the complex [Ni(CO)4]?

Practice Questions

Q1
What is the hybridization of the central atom in the complex [Ni(CO)4]?
  1. sp
  2. sp2
  3. sp3
  4. d2sp3

Questions & Step-by-Step Solutions

What is the hybridization of the central atom in the complex [Ni(CO)4]?
  • Step 1: Identify the central atom in the complex [Ni(CO)4]. The central atom is nickel (Ni).
  • Step 2: Determine the oxidation state of nickel in the complex. In [Ni(CO)4], CO is a neutral ligand, so the oxidation state of Ni is 0.
  • Step 3: Find the number of valence electrons for nickel. Nickel is in group 10 of the periodic table and has 10 valence electrons.
  • Step 4: Count the number of ligands attached to the central atom. There are four CO ligands attached to nickel.
  • Step 5: Determine the hybridization based on the number of ligands. Since there are four ligands, we use the formula for hybridization: number of ligands = number of hybrid orbitals needed. For four ligands, we need four hybrid orbitals.
  • Step 6: Identify the type of hybridization. Four hybrid orbitals correspond to sp3 hybridization.
  • Step 7: Conclude that the hybridization of the central atom nickel in [Ni(CO)4] is sp3.
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