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Which of the following compounds is least reactive towards electrophilic substit

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Question: Which of the following compounds is least reactive towards electrophilic substitution?

Options:

  1. Benzene
  2. Toluene
  3. Nitrobenzene
  4. Anisole

Correct Answer: Nitrobenzene

Solution: 

Nitrobenzene is least reactive towards electrophilic substitution due to the strong electron-withdrawing effect of the nitro group, which deactivates the ring.

Which of the following compounds is least reactive towards electrophilic substit

Practice Questions

Q1
Which of the following compounds is least reactive towards electrophilic substitution?
  1. Benzene
  2. Toluene
  3. Nitrobenzene
  4. Anisole

Questions & Step-by-Step Solutions

Which of the following compounds is least reactive towards electrophilic substitution?
  • Step 1: Understand what electrophilic substitution means. It is a reaction where an electrophile replaces a hydrogen atom in a benzene ring.
  • Step 2: Identify the compounds given in the question. Look for the one that has a nitro group (-NO2) attached to the benzene ring.
  • Step 3: Know that the nitro group is an electron-withdrawing group. This means it pulls electrons away from the benzene ring.
  • Step 4: Realize that when a group withdraws electrons, it makes the benzene ring less reactive towards electrophiles.
  • Step 5: Compare the reactivity of the compounds. The one with the nitro group will be the least reactive because it is deactivated by the strong electron-withdrawing effect.
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