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Which of the following complexes is an example of a square planar geometry?

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Question: Which of the following complexes is an example of a square planar geometry?

Options:

  1. [Ni(CN)4]2-
  2. [Co(NH3)6]3+
  3. [Fe(H2O)6]2+
  4. [CuCl4]2-

Correct Answer: [Ni(CN)4]2-

Solution:

[Ni(CN)4]2- is a square planar complex, while the others typically exhibit octahedral geometry.

Which of the following complexes is an example of a square planar geometry?

Practice Questions

Q1
Which of the following complexes is an example of a square planar geometry?
  1. [Ni(CN)4]2-
  2. [Co(NH3)6]3+
  3. [Fe(H2O)6]2+
  4. [CuCl4]2-

Questions & Step-by-Step Solutions

Which of the following complexes is an example of a square planar geometry?
  • Step 1: Understand what square planar geometry means. It is a shape where four atoms or groups are arranged at the corners of a square, with one atom in the center.
  • Step 2: Identify the complex in the question, which is [Ni(CN)4]2-. This means it has nickel (Ni) at the center and four cyanide (CN) groups attached to it.
  • Step 3: Recall that square planar geometry is common for certain metal complexes, especially those with d8 electron configuration like Ni(II).
  • Step 4: Compare [Ni(CN)4]2- with other complexes mentioned in the question. Most of them will have octahedral geometry, which has six groups around the central atom.
  • Step 5: Conclude that [Ni(CN)4]2- is indeed a square planar complex because it has four groups arranged in a square around the nickel.
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