What is the reduction half-reaction for the conversion of MnO4- to Mn2+ in acidi

Practice Questions

Q1
What is the reduction half-reaction for the conversion of MnO4- to Mn2+ in acidic medium?
  1. MnO4- + 8H+ + 5e- → Mn2+ + 4H2O
  2. MnO4- + 5e- → Mn2+ + 8H+ + 4H2O
  3. MnO4- + 4H2O + 5e- → Mn2+ + 8H+
  4. MnO4- + 5e- + 4H2O → Mn2+ + 8H+

Questions & Step-by-Step Solutions

What is the reduction half-reaction for the conversion of MnO4- to Mn2+ in acidic medium?
  • Step 1: Identify the species being reduced. In this case, it is MnO4- (permanganate ion).
  • Step 2: Determine the oxidation state of manganese in MnO4-. It is +7.
  • Step 3: Identify the final product, which is Mn2+. The oxidation state of manganese in Mn2+ is +2.
  • Step 4: Calculate the change in oxidation state. The change is from +7 to +2, which is a reduction of 5.
  • Step 5: Write the half-reaction for the reduction. Start with MnO4- and add electrons to balance the charge.
  • Step 6: Since we are in acidic medium, add H+ ions to balance the hydrogen atoms. We need 8 H+ ions.
  • Step 7: Add water (H2O) to balance the oxygen atoms. We will produce 4 H2O molecules.
  • Step 8: Combine all parts to form the complete reduction half-reaction: MnO4- + 8H+ + 5e- → Mn2+ + 4H2O.
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