For the equilibrium 2A(g) ⇌ B(g) + C(g), if the volume of the container is doubl

Practice Questions

Q1
For the equilibrium 2A(g) ⇌ B(g) + C(g), if the volume of the container is doubled, what will happen to the equilibrium position?
  1. Shift to the left
  2. Shift to the right
  3. No change
  4. Depends on the temperature

Questions & Step-by-Step Solutions

For the equilibrium 2A(g) ⇌ B(g) + C(g), if the volume of the container is doubled, what will happen to the equilibrium position?
  • Step 1: Understand the equilibrium reaction: 2A(g) ⇌ B(g) + C(g).
  • Step 2: Identify the number of gas moles on each side of the equation. The left side has 2 moles (2A) and the right side has 2 moles (1B + 1C).
  • Step 3: Recognize that doubling the volume of the container decreases the pressure of the gases inside.
  • Step 4: Apply Le Chatelier's principle, which states that if a system at equilibrium is disturbed, it will shift to counteract the disturbance.
  • Step 5: Since the pressure decreases, the equilibrium will shift towards the side with more moles of gas to increase the pressure.
  • Step 6: In this case, both sides have the same number of moles (2 moles), so the equilibrium position will not shift significantly.
  • Le Chatelier's Principle – This principle states that if an external change is applied to a system at equilibrium, the system will adjust to counteract that change and restore a new equilibrium.
  • Effect of Volume on Equilibrium – Changing the volume of a gas system affects the pressure; increasing the volume decreases the pressure, which can shift the equilibrium position depending on the number of moles of gas on each side.
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