Which of the following compounds is least acidic due to +M effect?

Practice Questions

Q1
Which of the following compounds is least acidic due to +M effect?
  1. Phenol
  2. Acetic acid
  3. Formic acid
  4. Benzoic acid

Questions & Step-by-Step Solutions

Which of the following compounds is least acidic due to +M effect?
  • Step 1: Understand what acidity means. Acidity refers to how easily a compound can donate a proton (H+).
  • Step 2: Identify the compounds being compared. In this case, we are looking at phenol and other acids.
  • Step 3: Learn about the +M effect. The +M effect (positive mesomeric effect) occurs when an electron-donating group (like an aromatic ring) stabilizes a negative charge.
  • Step 4: Recognize that phenol has an aromatic ring. This ring can donate electrons, which affects the stability of the phenoxide ion (the ion formed when phenol loses a proton).
  • Step 5: Compare the stability of the phenoxide ion to other acids. The +M effect from the aromatic ring makes the negative charge on the phenoxide ion less stable.
  • Step 6: Conclude that because the negative charge is destabilized by the +M effect, phenol is less acidic than the other acids listed.
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