Which of the following haloarenes is most reactive towards nucleophilic substitu

Practice Questions

Q1
Which of the following haloarenes is most reactive towards nucleophilic substitution?
  1. Chlorobenzene
  2. Bromobenzene
  3. Iodobenzene
  4. Fluorobenzene

Questions & Step-by-Step Solutions

Which of the following haloarenes is most reactive towards nucleophilic substitution?
  • Step 1: Understand what haloarenes are. Haloarenes are aromatic compounds that contain a halogen atom (like iodine, bromine, or chlorine) attached to a benzene ring.
  • Step 2: Know what nucleophilic substitution means. Nucleophilic substitution is a reaction where a nucleophile (a species that donates an electron pair) replaces a leaving group (like a halogen) in a compound.
  • Step 3: Identify the haloarenes in the question. The haloarenes mentioned are iodobenzene, bromobenzene, and chlorobenzene.
  • Step 4: Compare the C-X bonds (where X is the halogen) in these haloarenes. Iodobenzene has a C-I bond, bromobenzene has a C-Br bond, and chlorobenzene has a C-Cl bond.
  • Step 5: Understand bond strength. The C-I bond is weaker than the C-Br and C-Cl bonds. This means it is easier to break the C-I bond.
  • Step 6: Conclude that since the C-I bond is weaker, iodobenzene will react more easily in nucleophilic substitution compared to bromobenzene and chlorobenzene.
  • Step 7: Therefore, iodobenzene is the most reactive haloarene towards nucleophilic substitution.
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