What is the relationship between enthalpy change and the spontaneity of a reacti

Practice Questions

Q1
What is the relationship between enthalpy change and the spontaneity of a reaction?
  1. A negative enthalpy change guarantees spontaneity
  2. A positive enthalpy change guarantees spontaneity
  3. Enthalpy change does not affect spontaneity
  4. Spontaneity depends on enthalpy and entropy changes

Questions & Step-by-Step Solutions

What is the relationship between enthalpy change and the spontaneity of a reaction?
  • Step 1: Understand that spontaneity means whether a reaction will happen on its own without outside help.
  • Step 2: Learn about enthalpy, which is the heat content of a system. A reaction can release heat (exothermic) or absorb heat (endothermic).
  • Step 3: Know that a negative enthalpy change (heat released) often favors spontaneity.
  • Step 4: Understand that entropy is a measure of disorder or randomness in a system. A positive entropy change (more disorder) also favors spontaneity.
  • Step 5: Learn about the Gibbs free energy equation: ΔG = ΔH - TΔS, where ΔG is the change in Gibbs free energy, ΔH is the change in enthalpy, T is the temperature in Kelvin, and ΔS is the change in entropy.
  • Step 6: Realize that if ΔG is negative, the reaction is spontaneous. This means that both ΔH and ΔS play a role in determining spontaneity.
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