Physical Chemistry

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Physical Chemistry MCQ & Objective Questions

Physical Chemistry is a crucial branch of chemistry that combines principles of physics and chemistry to explain how matter behaves. Mastering this subject is essential for students preparing for school exams and competitive tests. Practicing MCQs and objective questions in Physical Chemistry not only enhances conceptual clarity but also boosts your chances of scoring better in exams. Engaging with practice questions helps identify important topics and reinforces learning.

What You Will Practise Here

  • Thermodynamics: Laws, concepts, and applications
  • Kinetics: Rate laws, reaction mechanisms, and factors affecting reaction rates
  • Equilibrium: Chemical equilibrium, Le Chatelier's principle, and equilibrium constants
  • Quantum Chemistry: Basic principles and applications in atomic structure
  • Electrochemistry: Redox reactions, electrochemical cells, and Nernst equation
  • Solutions: Colligative properties and their calculations
  • Acids and Bases: pH calculations, buffer solutions, and titration curves

Exam Relevance

Physical Chemistry is a significant part of the syllabus for CBSE, State Boards, NEET, and JEE. Questions often focus on theoretical concepts, numerical problems, and application-based scenarios. Common patterns include direct questions on laws of thermodynamics, calculations involving reaction rates, and conceptual questions on equilibrium. Familiarity with these patterns can greatly enhance your exam preparation.

Common Mistakes Students Make

  • Misunderstanding the application of thermodynamic laws in different scenarios
  • Confusing reaction rates with equilibrium constants
  • Overlooking the significance of units in calculations
  • Neglecting to practice numerical problems, leading to poor time management during exams

FAQs

Question: What are the key topics to focus on in Physical Chemistry for exams?
Answer: Focus on thermodynamics, kinetics, equilibrium, and electrochemistry as these are frequently tested.

Question: How can I improve my performance in Physical Chemistry MCQs?
Answer: Regular practice of MCQs and understanding the underlying concepts will significantly improve your performance.

Now is the time to enhance your understanding of Physical Chemistry! Dive into our practice MCQs and test your knowledge to excel in your exams. Your success starts with practice!

Q. A ladder leans against a wall and is in equilibrium. What forces are acting on the ladder?
  • A. Weight, normal force from the ground, and friction
  • B. Only weight and normal force
  • C. Only weight and friction
  • D. Only normal force and friction
Q. A particle is in equilibrium under the action of three forces. If two forces are known, how can the third force be determined?
  • A. By vector addition of the first two forces
  • B. By subtracting the first two forces
  • C. By multiplying the first two forces
  • D. By taking the average of the first two forces
Q. A solution contains 20% (w/w) of glucose. If the total mass of the solution is 200 g, what is the mass of glucose in the solution?
  • A. 20 g
  • B. 40 g
  • C. 60 g
  • D. 80 g
Q. A solution has a concentration of 0.1 M NaCl. How many grams of NaCl are present in 1 liter of this solution? (Molar mass of NaCl = 58.5 g/mol)
  • A. 5.85 g
  • B. 58.5 g
  • C. 0.1 g
  • D. 0.585 g
Q. A solution has a concentration of 0.2 M. How many moles of solute are present in 1.5 L of this solution?
  • A. 0.3 moles
  • B. 0.5 moles
  • C. 0.2 moles
  • D. 0.15 moles
Q. A solution has a density of 1.2 g/mL and contains 10% (w/v) NaCl. What is the mass of NaCl in 1 liter of this solution?
  • A. 100 g
  • B. 120 g
  • C. 80 g
  • D. 60 g
Q. A solution has a density of 1.2 g/mL and contains 10% (w/v) NaOH. What is the mass of NaOH in 1 L of this solution?
  • A. 100 g
  • B. 120 g
  • C. 80 g
  • D. 60 g
Q. A solution has a density of 1.2 g/mL and contains 30 g of solute. What is the molarity if the molar mass of the solute is 60 g/mol?
  • A. 0.5 M
  • B. 1 M
  • C. 2 M
  • D. 1.5 M
Q. A solution is prepared by dissolving 50 g of glucose (C6H12O6) in 250 g of water. What is the mass percent of glucose in the solution? (Molar mass of glucose = 180 g/mol)
  • A. 20%
  • B. 15%
  • C. 25%
  • D. 10%
Q. A solution is prepared by dissolving 58.5 g of NaCl in 1 L of water. What is the concentration in terms of molarity? (Molar mass of NaCl = 58.5 g/mol)
  • A. 1 M
  • B. 2 M
  • C. 0.5 M
  • D. 0.25 M
Q. A solution is prepared by dissolving 58.5 g of NaCl in 1 L of water. What is the molarity of the solution? (Molar mass of NaCl = 58.5 g/mol)
  • A. 1 M
  • B. 2 M
  • C. 0.5 M
  • D. 0.1 M
Q. A solution is prepared by dissolving 58.5 g of NaCl in enough water to make 1 L of solution. What is the molarity of the solution? (Molar mass of NaCl = 58.5 g/mol)
  • A. 1 M
  • B. 2 M
  • C. 0.5 M
  • D. 0.1 M
Q. A solution of 0.1 molal urea in water has a freezing point depression of how much? (K_f for water = 1.86 °C kg/mol)
  • A. 0.186 °C
  • B. 0.372 °C
  • C. 0.186 K
  • D. 0.372 K
Q. According to Boyle's law, if the volume of a gas is doubled at constant temperature, what happens to the pressure?
  • A. It doubles
  • B. It halves
  • C. It remains constant
  • D. It quadruples
Q. According to Boyle's law, if the volume of a gas is doubled, what happens to its pressure?
  • A. It doubles
  • B. It halves
  • C. It remains constant
  • D. It quadruples
Q. According to Graham's law of effusion, the rate of effusion of a gas is inversely proportional to what?
  • A. Molar mass
  • B. Temperature
  • C. Pressure
  • D. Volume
Q. According to the ideal gas law, which of the following is the correct equation?
  • A. PV = nRT
  • B. PV = nR
  • C. P = nRT/V
  • D. V = nP/RT
Q. According to the kinetic molecular theory, which of the following statements is true?
  • A. Gas particles have significant volume.
  • B. Gas particles are in constant motion.
  • C. Gas particles attract each other.
  • D. Gas particles do not collide.
Q. According to VSEPR theory, what is the shape of the molecule with the formula AX2E2?
  • A. Linear
  • B. Bent
  • C. Trigonal planar
  • D. Tetrahedral
Q. At constant temperature and pressure, if ΔH is positive and ΔS is negative, what can be said about ΔG?
  • A. ΔG is positive
  • B. ΔG is negative
  • C. ΔG is zero
  • D. ΔG can be either positive or negative
Q. At constant temperature and pressure, if ΔH is positive and ΔS is negative, what is the sign of ΔG?
  • A. Always negative
  • B. Always positive
  • C. Depends on temperature
  • D. Zero
Q. At constant temperature, the volume of a gas is inversely proportional to its pressure. This is known as which law?
  • A. Boyle's Law
  • B. Charles's Law
  • C. Avogadro's Law
  • D. Ideal Gas Law
Q. At what temperature does a reaction become spontaneous if ΔH = 50 kJ and ΔS = 0.1 kJ/K?
  • A. 500 K
  • B. 250 K
  • C. 1000 K
  • D. 200 K
Q. At what temperature does the Gibbs Free Energy change from negative to positive?
  • A. At absolute zero
  • B. At the melting point
  • C. At the boiling point
  • D. At the transition temperature
Q. At what temperature does the volume of a gas become zero according to Charles's Law?
  • A. 0 K
  • B. -273.15 °C
  • C. 273.15 K
  • D. None of the above
Q. Calculate the molality of a solution if the boiling point elevation is 1.024 °C. (K_b for water = 0.512 °C kg/mol)
  • A. 1 mol/kg
  • B. 2 mol/kg
  • C. 0.5 mol/kg
  • D. 0.25 mol/kg
Q. Calculate the pH of a 0.1 M acetic acid solution (Ka = 1.8 x 10^-5).
  • A. 2.87
  • B. 3.87
  • C. 4.87
  • D. 5.87
Q. Calculate the pH of a buffer solution containing 0.1 M acetic acid and 0.1 M sodium acetate.
  • A. 4.76
  • B. 5.76
  • C. 6.76
  • D. 7.76
Q. Calculate the pH of a solution that is 0.1 M in acetic acid (Ka = 1.8 x 10^-5).
  • A. 2.87
  • B. 3.87
  • C. 4.87
  • D. 5.87
Q. Determine the hybridization of the central atom in BF3.
  • A. sp
  • B. sp2
  • C. sp3
  • D. dsp3
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