Functional Groups and Nomenclature - Advanced Concepts

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This section explores complex functional group chemistry and systematic nomenclature rules, with a focus on multi-functional and substituted organic compounds. It is designed for Class 11–12 students, competitive exam aspirants, and undergraduate learners who seek a deeper understanding of organic structure, reactivity, and IUPAC naming conventions.

In this section, you will study:

  • Advanced IUPAC rules for naming multi-functional compounds

  • Functional group priority and hierarchy in nomenclature

  • Nomenclature of polyfunctional, branched, and cyclic compounds

  • Substituted aromatic compounds and heterocyclic systems

  • Strategies to deduce correct names for complex molecules

  • Common pitfalls in advanced naming scenarios

  • Integration of functional group properties with structure for reactivity prediction

  • NCERT-aligned advanced examples, diagrams, MCQs, and exam-oriented questions

The content is structured to enhance conceptual depth, strengthen analytical and logical reasoning, and prepare students to confidently tackle high-order and tricky questions in school exams, NEET, JEE, and undergraduate assessments.

Develop a strong mastery of advanced functional group nomenclature to systematically name complex organic molecules and link structure to chemical behavior.

Q. What is the correct IUPAC name for CH3-CH2-COOH?
  • A. Propanoic acid
  • B. Butanoic acid
  • C. Acetic acid
  • D. Isobutyric acid
Q. What is the correct IUPAC name for the compound with the structure CH3-CH(CH3)-C(=O)-OH?
  • A. 3-Methylbutanoic acid
  • B. 2-Methylbutanoic acid
  • C. 2-Hydroxy-3-methylbutanoic acid
  • D. 3-Hydroxy-2-methylbutanoic acid
Q. What is the functional group of esters?
  • A. Aldehyde
  • B. Carboxyl
  • C. Ester
  • D. Amine
Q. What is the IUPAC name for the compound with the formula C5H10O2 that contains an ester functional group?
  • A. Pentanoic acid
  • B. Ethyl butanoate
  • C. Butyl acetate
  • D. 2-Pentenoic acid
Q. What is the stereochemical configuration of 2-bromo-3-methylpentane at the chiral center?
  • A. R
  • B. S
  • C. E
  • D. Z
Q. Which functional group is present in the compound CH3CH2COOH?
  • A. Alcohol
  • B. Aldehyde
  • C. Carboxylic acid
  • D. Ester
Q. Which of the following functional groups is present in carboxylic acids?
  • A. Aldehyde
  • B. Alcohol
  • C. Carboxyl
  • D. Ester
Q. Which of the following is a feature of stereoisomers?
  • A. Same molecular formula, different connectivity
  • B. Different molecular formulas
  • C. Same connectivity, different spatial arrangement
  • D. Same physical properties
Q. Which reaction mechanism is involved in the conversion of an alcohol to an alkyl halide?
  • A. SN1
  • B. SN2
  • C. E1
  • D. E2
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