Aromatic Compounds and Electrophilic Substitution - Numerical Applications

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This section focuses on numerical, quantitative, and data-based problems related to aromatic compounds and electrophilic aromatic substitution (EAS) reactions. It is designed for Class 11–12 students, competitive exam aspirants, and undergraduate learners to apply aromatic chemistry concepts through calculations, rate comparisons, and data interpretation.

In this section, you will practice:

  • Numerical problems based on reaction rate comparisons in EAS

  • Quantitative analysis of activating and deactivating substituent effects

  • Data interpretation from experimental reactivity tables

  • Problems involving energy profiles and σ-complex stability

  • Calculation-based comparison of ortho, meta, and para substitution outcomes

  • Graph- and table-based problems related to aromatic reactivity

  • NCERT-aligned numerical and logic-based exam questions

The content is structured to improve quantitative reasoning, enhance data interpretation, and help students confidently handle numerical and analytical questions in school examinations, JEE-type exams, and undergraduate assessments.

Develop accuracy and confidence in solving numerical applications related to aromatic compounds and electrophilic substitution through systematic and exam-focused practice.

Q. In the nitration of toluene, which product is formed predominantly?
  • A. Nitrotoluene (ortho)
  • B. Nitrotoluene (para)
  • C. Dinitrotoluene
  • D. Benzyl nitrite
Q. In the nitration of toluene, which product is predominantly formed?
  • A. Nitrotoluene
  • B. Dinitrotoluene
  • C. Benzyl alcohol
  • D. Toluene sulfonic acid
Q. In the presence of a strong electrophile, which aromatic compound will undergo substitution the fastest?
  • A. Benzene
  • B. Phenol
  • C. Aniline
  • D. Toluene
Q. In the presence of sulfuric acid, what is the product of the electrophilic substitution of benzene with sulfur trioxide?
  • A. Benzene sulfonic acid
  • B. Benzene thiosulfate
  • C. Benzene sulfide
  • D. Benzene disulfide
Q. What is the expected product when phenol is treated with bromine water?
  • A. Bromobenzene
  • B. 2,4,6-Tribromophenol
  • C. Benzene
  • D. Bromophenol
Q. What is the IUPAC name of the compound formed when benzene undergoes sulfonation with sulfuric acid?
  • A. Benzene sulfonic acid
  • B. Benzene thiosulfate
  • C. Benzene sulfate
  • D. Benzene disulfide
Q. Which of the following compounds is a stronger electrophile in electrophilic aromatic substitution?
  • A. Benzene
  • B. Nitrobenzene
  • C. Toluene
  • D. Chlorobenzene
Q. Which of the following compounds is the most reactive towards electrophilic substitution?
  • A. Benzene
  • B. Toluene
  • C. Chlorobenzene
  • D. Nitrobenzene
Q. Which of the following compounds will not undergo electrophilic substitution?
  • A. Benzene
  • B. Toluene
  • C. Nitrobenzene
  • D. Phenol
Q. Which of the following compounds will undergo electrophilic substitution the fastest?
  • A. Benzene
  • B. Ethylbenzene
  • C. Chlorobenzene
  • D. Nitrobenzene
Q. Which position on a disubstituted benzene ring will a new substituent most likely attach if one substituent is a strong electron-donating group and the other is a weak electron-withdrawing group?
  • A. Ortho
  • B. Meta
  • C. Para
  • D. None
Q. Which position on the benzene ring does a nitro group preferentially substitute when starting from nitrobenzene?
  • A. Ortho
  • B. Meta
  • C. Para
  • D. All positions equally
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