Aromatic Compounds and Electrophilic Substitution - Problem Set

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This problem set provides structured, comprehensive, and exam-oriented practice on aromatic compounds and electrophilic aromatic substitution reactions. It is designed for Class 11–12 students, competitive exam aspirants, and undergraduate learners to strengthen conceptual clarity through systematic problem solving.

In this section, you will practice:

  • Concept-based questions on aromaticity and resonance

  • Mechanism-focused problems on electrophilic aromatic substitution

  • MCQs aligned with NCERT, JEE-type, and UG exam patterns

  • Assertion–reason and multi-statement questions

  • Problems on directing effects and regioselectivity

  • Numerical and data-interpretation questions

  • Mixed-difficulty problems from basic to advanced levels

The problem set is structured to support progressive skill development, improve reaction analysis, and help students assess their readiness for school exams, competitive entrances, and undergraduate assessments.

Strengthen your mastery of aromatic compounds and electrophilic substitution by consistent and focused problem-solving practice.

Q. In the nitration of benzene, which reagent is used to generate the nitronium ion (NO2+)?
  • A. HNO3
  • B. H2SO4
  • C. HCl
  • D. NaNO2
Q. What is the product of the Friedel-Crafts acylation of benzene with acetyl chloride (CH3COCl)?
  • A. Acetophenone
  • B. Benzophenone
  • C. Benzyl acetate
  • D. Phenyl acetate
Q. What is the stereochemistry of the product formed from the electrophilic substitution of 1,2-dimethylbenzene (o-xylene)?
  • A. R
  • B. S
  • C. R and S
  • D. None
Q. Which of the following compounds will undergo electrophilic substitution more readily?
  • A. Benzene
  • B. Toluene
  • C. Chlorobenzene
  • D. Nitrobenzene
Q. Which of the following is a common electrophile used in electrophilic aromatic substitution reactions?
  • A. Bromine
  • B. Benzene
  • C. Alkane
  • D. Alkene
Q. Which substituent on a benzene ring is considered an electron-donating group?
  • A. Nitro group
  • B. Hydroxyl group
  • C. Carboxylic acid
  • D. Halogen
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