Electrochemistry Advanced

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This chapter explores the advanced principles, quantitative calculations, and practical applications of electrochemical systems, providing an in-depth understanding of redox processes, electrode potentials, and electrochemical cells. It is designed for Class 11–12 students, competitive exam aspirants, and undergraduate learners seeking analytical mastery in electrochemistry.

In this section, you will study:

  • Electrochemical cells: galvanic and electrolytic cells

  • Standard electrode potentials and their measurement

  • Nernst equation and application in non-standard conditions

  • Relationship between Gibbs free energy, equilibrium, and cell potential

  • Quantitative aspects of electrolysis (Faraday’s laws)

  • Concentration cells and overpotential considerations

  • Electrode kinetics and real-cell deviations

  • Applications in corrosion, batteries, fuel cells, and electroplating

  • NCERT-aligned explanations, diagrams, numerical problems, and exam-oriented questions

The content is structured to strengthen conceptual understanding, enhance mathematical and analytical skills, and prepare students to tackle high-level problems in school examinations, JEE, NEET, and undergraduate assessments.

Develop advanced competence in electrochemistry to predict, analyze, and solve complex theoretical and practical problems in redox chemistry and electrochemical applications.

Q. In a galvanic cell, which electrode is the site of reduction?
  • A. Anode
  • B. Cathode
  • C. Salt bridge
  • D. Electrolyte
Q. What is the IUPAC name for the compound CH₃-CH₂-CH(CH₃)-CH₂OH?
  • A. 2-Butanol
  • B. 3-Pentanol
  • C. 1-Butanol
  • D. 2-Pentanol
Q. What is the IUPAC name for the compound with the formula CH₃COOH?
  • A. Acetic acid
  • B. Ethanoic acid
  • C. Propanoic acid
  • D. Butanoic acid
Q. What is the main function of a salt bridge in an electrochemical cell?
  • A. To provide a source of electrons
  • B. To maintain electrical neutrality
  • C. To increase the reaction rate
  • D. To separate the electrodes
Q. What is the primary product of the electrolysis of aqueous NaCl?
  • A. Hydrogen gas
  • B. Chlorine gas
  • C. Sodium hydroxide
  • D. Sodium chloride
Q. What is the standard electrode potential of the half-reaction: Cu²⁺ + 2e⁻ → Cu?
  • A. +0.34 V
  • B. +0.76 V
  • C. -0.34 V
  • D. -0.76 V
Q. What is the stereochemical configuration of 2-butanol?
  • A. R
  • B. S
  • C. R and S
  • D. Neither
Q. Which biomolecule is primarily responsible for energy storage in cells?
  • A. Proteins
  • B. Nucleic acids
  • C. Carbohydrates
  • D. Lipids
Q. Which biomolecule is primarily responsible for energy storage in living organisms?
  • A. Proteins
  • B. Carbohydrates
  • C. Lipids
  • D. Nucleic acids
Q. Which functional group is characterized by a carbonyl group (C=O) bonded to a hydroxyl group (–OH)?
  • A. Alcohol
  • B. Aldehyde
  • C. Carboxylic acid
  • D. Ketone
Q. Which of the following is a characteristic of electrochemical cells?
  • A. They convert chemical energy to electrical energy
  • B. They only operate in acidic solutions
  • C. They require a constant supply of reactants
  • D. They cannot be reversed
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