D & F Block Elements

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This chapter covers the structure, properties, and chemical behavior of transition and inner transition elements. It is a core topic in school and undergraduate chemistry, essential for Class 12 students, competitive exam aspirants, and undergraduate learners, forming the foundation for understanding metallic chemistry, complex formation, and redox behavior.

In this section, you will study:

  • General characteristics of d-block (transition) elements

  • Electronic configuration, oxidation states, and trends in properties

  • Magnetic properties, color, and catalytic activity of transition metals

  • Formation and properties of coordination compounds

  • Chemistry of f-block (lanthanides and actinides)

  • Comparison of d- and f-block elements in terms of reactivity and stability

  • NCERT-aligned explanations, diagrams, MCQs, and exam-oriented questions

The content is structured to build conceptual clarity, improve analytical reasoning, and prepare students for school examinations, NEET, JEE, and undergraduate assessments.

Develop a strong foundation in transition and inner transition element chemistry to understand their structure, bonding, and unique chemical behavior.

Q. What is the geometry of the complex ion [Cu(NH3)4]SO4?
  • A. Tetrahedral
  • B. Square planar
  • C. Octahedral
  • D. Trigonal bipyramidal
Q. What is the hybridization of the central atom in the complex [Ni(CO)4]?
  • A. sp
  • B. sp2
  • C. sp3
  • D. d2sp3
Q. What is the IUPAC name of the compound with the formula [Co(NH3)5Cl]Cl2?
  • A. Pentaamminechlorocobalt(III) chloride
  • B. Chloropentaamminecobalt(II) chloride
  • C. Pentaamminecobalt(II) chloride
  • D. Pentaamminechlorocobalt(II) chloride
Q. What is the IUPAC name of the compound [Cr(NH3)6]Cl3?
  • A. Hexaammonium chromium(III) chloride
  • B. Hexaammonia chromium(III) chloride
  • C. Hexaammine chromium(III) chloride
  • D. Hexaammonium chromium(II) chloride
Q. What is the oxidation state of iron in the complex [Fe(CN)6]3-?
  • A. +2
  • B. +3
  • C. +4
  • D. +1
Q. Which of the following compounds is a common oxidation state of iron?
  • A. +1
  • B. +2
  • C. +3
  • D. +4
Q. Which of the following elements is a lanthanide?
  • A. Zirconium
  • B. Neodymium
  • C. Tantalum
  • D. Hafnium
Q. Which of the following is a characteristic of f-block elements?
  • A. They are all radioactive
  • B. They have partially filled f-orbitals
  • C. They are all metals
  • D. They have low density
Q. Which of the following is a property of d-block elements?
  • A. Forming ionic bonds only
  • B. High melting and boiling points
  • C. Always being paramagnetic
  • D. Being non-metals
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