Hydrogen and its Compounds - Higher Difficulty Problems

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The Hydrogen and Its Compounds – Higher Difficulty Problems section is designed to challenge students with multi-concept, high-thinking-level problems commonly encountered in JEE Advanced, Olympiads, CUET-UG (top percentile), and undergraduate chemistry examinations. This module goes beyond routine questions and emphasizes deep conceptual linkage, logical elimination, and exception handling.

In this section, you will solve problems involving:

  • Comparative behavior of hydrogen with alkali metals and halogens under different chemical environments

  • Advanced hydride stability problems involving lattice energy, covalency, and periodic trends

  • Multi-step reaction pathways of hydrogen, water, and hydrogen peroxide

  • Redox-intensive problems based on the dual nature of hydrogen and H₂O₂

  • Hydrogen bonding anomalies – boiling point, viscosity, and structure-property relationships

  • Water chemistry puzzles – density anomaly, solvation effects, and dielectric reasoning

  • Interlinked conceptual traps drawn from NCERT footnotes and exceptions

  • Assertion–reason and matrix-match problems requiring elimination logic

  • Graph- and data-based questions involving stability, enthalpy, and reaction feasibility

The content is structured to strengthen analytical depth, improve logical accuracy under pressure, and prepare students for high-stakes, non-routine examination questions.

Master these higher-difficulty problems to develop the confidence needed for top-rank performance in Inorganic Chemistry, especially in the chapter Hydrogen and Its Compounds.

Q. In which of the following coordination compounds does hydrogen act as a ligand?
  • A. [Fe(H2O)6]2+
  • B. [Cu(NH3)4]2+
  • C. [CoCl4]2-
  • D. [Ag(CN)2]-
Q. What is the main reason for the low boiling point of hydrogen compared to other group 1 hydrides?
  • A. Hydrogen forms stronger bonds
  • B. Hydrogen has a lower molecular weight
  • C. Hydrogen does not form hydrogen bonds
  • D. Hydrogen is a gas at room temperature
Q. What is the oxidation state of hydrogen in the compound H2SO4?
  • A. 0
  • B. +1
  • C. -1
  • D. +2
Q. What is the oxidation state of hydrogen in the hydride ion (H-)?
  • A. 0
  • B. +1
  • C. -1
  • D. +2
Q. What is the primary reason for the high electronegativity of hydrogen compared to alkali metals?
  • A. It has a full outer shell
  • B. It has a small atomic radius
  • C. It can form multiple bonds
  • D. It is a non-metal
Q. Which of the following compounds is a strong acid derived from hydrogen?
  • A. HCl
  • B. H2O
  • C. NH3
  • D. CH4
Q. Which of the following hydrogen compounds is most likely to act as a Lewis acid?
  • A. H2O
  • B. HCl
  • C. B2H6
  • D. NH3
Q. Which of the following hydrogen compounds is most likely to act as a reducing agent?
  • A. H2O
  • B. H2S
  • C. HCl
  • D. H2O2
Q. Which of the following is a characteristic of hydrogen as a metalloid?
  • A. It conducts electricity
  • B. It has a high melting point
  • C. It can form cations
  • D. It is malleable
Q. Which of the following is a characteristic of hydrogen peroxide (H2O2)?
  • A. It is a strong acid
  • B. It acts as a reducing agent
  • C. It is a stable compound
  • D. It contains a single bond between oxygen atoms
Q. Which of the following reactions is an example of a redox reaction involving hydrogen?
  • A. H2 + O2 → H2O
  • B. HCl + NaOH → NaCl + H2O
  • C. H2 + Cl2 → 2HCl
  • D. H2 + CO2 → H2O + C
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