Transition Elements and Coordination Chemistry Basics

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The Transition Elements and Coordination Chemistry – Basics section introduces the fundamental principles governing transition metals and coordination compounds, which form the backbone of modern inorganic chemistry, industrial catalysis, and bioinorganic systems. This module is designed for Class 11–12 students, undergraduate learners, and competitive exam aspirants, with emphasis on conceptual clarity, definitions, and structural understanding.

In this section, you will study:

  • Definition and general characteristics of transition elements

  • Electronic configuration of d-block elements and their periodic trends

  • Common oxidation states and variable valency of transition metals

  • Formation and nature of coordination compounds

  • Ligands and coordination number – basic classification and examples

  • Nomenclature of coordination compounds (IUPAC basics)

  • Bonding concepts (introductory) – Werner’s theory and basic ideas of metal–ligand bonding

  • Magnetic properties (introductory) – paramagnetism and diamagnetism

  • Color of transition metal ions – basic explanation using d–d transitions

  • Simple coordination geometries – octahedral, tetrahedral, and square planar

  • NCERT-aligned explanations, supported by diagrams, tables, examples, and basic MCQs

The content is structured to build a strong conceptual base, enabling students to understand advanced d-block chemistry, coordination theory, and applications covered in later chapters.

Master these basic concepts of Transition Elements and Coordination Chemistry to lay a solid foundation for advanced inorganic chemistry, competitive exams, and real-world chemical applications.

Q. In the context of redox reactions, which transition metal is commonly used as a reducing agent?
  • A. Manganese
  • B. Iron
  • C. Copper
  • D. Silver
Q. What is the coordination number of the central metal ion in the complex [Cu(NH3)4]SO4?
  • A. 2
  • B. 4
  • C. 6
  • D. 8
Q. What is the effect of increasing the oxidation state of a transition metal on its ability to act as a Lewis acid?
  • A. Increases
  • B. Decreases
  • C. No effect
  • D. Varies unpredictably
Q. What is the oxidation state of chromium in the complex [Cr(NH3)6]Cl3?
  • A. +2
  • B. +3
  • C. +4
  • D. +6
Q. What is the primary reason for the catalytic activity of transition metals?
  • A. High atomic mass
  • B. Variable oxidation states
  • C. Low ionization energy
  • D. High electronegativity
Q. What type of isomerism is exhibited by the complex [Co(NH3)4Cl2]Cl?
  • A. Geometric
  • B. Optical
  • C. Linkage
  • D. Coordination
Q. Which of the following complexes is an example of a square planar geometry?
  • A. [Ni(CN)4]2-
  • B. [Co(NH3)6]3+
  • C. [Fe(H2O)6]2+
  • D. [CuCl4]2-
Q. Which of the following is a characteristic of a coordination compound?
  • A. It contains only ionic bonds.
  • B. It has a central metal atom bonded to ligands.
  • C. It cannot conduct electricity.
  • D. It is always a solid.
Q. Which of the following statements about transition metals is true?
  • A. They have completely filled d-orbitals.
  • B. They can form colored compounds.
  • C. They do not form complexes.
  • D. They have low melting points.
Q. Which of the following transition metals has the highest melting point?
  • A. Iron
  • B. Tungsten
  • C. Nickel
  • D. Copper
Q. Which of the following transition metals is known for its ability to form stable complexes with ligands?
  • A. Zinc
  • B. Copper
  • C. Iron
  • D. Nickel
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