The Intro to Spectroscopy (UV–Vis, IR) – Advanced Concepts section explores the theoretical depth, molecular interpretation, and quantitative treatment of spectroscopic techniques used in chemical analysis. This module is designed for undergraduate Chemistry students and advanced school learners, with emphasis on mechanistic understanding, spectral reasoning, and exam-oriented problem solving.
In this section, you will study:
Advanced theory of electromagnetic radiation–matter interaction
Electronic transitions in UV–Vis spectroscopy – σ→σ*, π→π*, n→π*, n→σ* transitions and selection rules
Chromophores and auxochromes – bathochromic and hypsochromic shifts, hyperchromic and hypochromic effects
Quantitative UV–Vis analysis – deviations from Beer–Lambert law and multicomponent analysis (introductory)
Vibrational theory in IR spectroscopy – harmonic vs anharmonic oscillators, fundamental vibrations, and overtones
Effect of molecular structure on IR absorption – bond strength, reduced mass, hydrogen bonding, and conjugation
IR spectral interpretation at UG level – fingerprint region analysis and functional group correlations
Instrumental factors affecting resolution, sensitivity, and accuracy
NCERT- and UG-aligned explanations, supported by derivations, spectral problem sets, assertion–reason MCQs, and PYQs
The content is structured to strengthen theoretical insight, improve spectral interpretation skills, and prepare students for UG examinations, viva voce, and competitive-level spectroscopy questions.
Develop a rigorous and analytical understanding of UV–Vis and IR spectroscopy to confidently interpret complex spectra and advanced analytical problems.
Q. In IR spectroscopy, what type of molecular vibrations are typically observed?
A.
Translational vibrations
B.
Rotational vibrations
C.
Stretching and bending vibrations
D.
Electronic transitions
Solution
IR spectroscopy detects molecular vibrations, specifically stretching and bending of bonds, which occur at characteristic frequencies.
Correct Answer:
C
— Stretching and bending vibrations