Electrochemistry
Q. In a concentration cell, the potential difference arises due to:
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A.
Different temperatures
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B.
Different concentrations
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C.
Different pressures
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D.
Different materials
Solution
In a concentration cell, the potential difference arises due to different concentrations of the same species.
Correct Answer: B — Different concentrations
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Q. In a Daniell cell, which metal is oxidized?
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A.
Copper
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B.
Zinc
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C.
Lead
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D.
Silver
Solution
In a Daniell cell, zinc is oxidized.
Correct Answer: B — Zinc
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Q. In a galvanic cell, the anode is where:
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A.
Reduction occurs
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B.
Oxidation occurs
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C.
Electrons are gained
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D.
The salt bridge is located
Solution
In a galvanic cell, oxidation occurs at the anode.
Correct Answer: B — Oxidation occurs
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Q. In electrochemistry, what does the term 'reduction' refer to?
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A.
Loss of electrons
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B.
Gain of electrons
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C.
Loss of protons
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D.
Gain of protons
Solution
Reduction refers to the gain of electrons in a chemical reaction.
Correct Answer: B — Gain of electrons
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Q. What is the effect of increasing temperature on the cell potential according to the Nernst equation?
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A.
Increases cell potential
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B.
Decreases cell potential
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C.
No effect
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D.
Depends on the reaction
Solution
The effect of increasing temperature on cell potential depends on the reaction and its enthalpy change.
Correct Answer: D — Depends on the reaction
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Q. What is the effect of increasing temperature on the cell potential?
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A.
Increases
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B.
Decreases
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C.
Remains constant
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D.
Depends on the reaction
Solution
The effect of temperature on cell potential depends on the reaction and its enthalpy change.
Correct Answer: D — Depends on the reaction
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Q. What is the main function of a salt bridge in a galvanic cell?
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A.
To provide a path for electrons
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B.
To maintain charge balance
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C.
To increase voltage
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D.
To decrease resistance
Solution
The main function of a salt bridge is to maintain charge balance by allowing ions to flow.
Correct Answer: B — To maintain charge balance
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Q. What is the Nernst equation used for?
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A.
Calculating pH
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B.
Determining cell potential
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C.
Finding molarity
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D.
Measuring temperature
Solution
The Nernst equation is used to determine the cell potential under non-standard conditions.
Correct Answer: B — Determining cell potential
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Q. What is the primary function of a cathode in an electrochemical cell?
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A.
To oxidize species
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B.
To reduce species
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C.
To provide electrons
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D.
To balance charge
Solution
The cathode is where reduction occurs, gaining electrons in the process.
Correct Answer: B — To reduce species
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Q. What is the primary function of a salt bridge in a galvanic cell?
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A.
To provide a path for electrons
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B.
To maintain charge balance
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C.
To increase voltage
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D.
To decrease resistance
Solution
The primary function of a salt bridge is to maintain charge balance by allowing ions to flow between the half-cells.
Correct Answer: B — To maintain charge balance
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Q. What is the primary reaction occurring in a lead-acid battery during discharge?
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A.
Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O
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B.
PbSO4 + 2H2O → Pb + PbO2 + 2H2SO4
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C.
2Pb + 2H2SO4 → 2PbSO4 + H2
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D.
PbO2 + 2H2SO4 → Pb + 2H2O + O2
Solution
During discharge, the primary reaction in a lead-acid battery is Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O.
Correct Answer: A — Pb + PbO2 + 2H2SO4 → 2PbSO4 + 2H2O
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Q. What is the role of a salt bridge in a galvanic cell?
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A.
To provide a pathway for electrons
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B.
To maintain charge balance
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C.
To increase voltage
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D.
To decrease resistance
Solution
The salt bridge maintains charge balance by allowing ions to flow between the two half-cells.
Correct Answer: B — To maintain charge balance
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Q. What is the role of the cathode in an electrochemical cell?
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A.
Oxidation occurs
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B.
Reduction occurs
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C.
Electrons are lost
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D.
Ions are produced
Solution
In an electrochemical cell, reduction occurs at the cathode.
Correct Answer: B — Reduction occurs
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Q. What is the standard electrode potential of the hydrogen electrode?
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A.
0.00 V
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B.
0.34 V
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C.
1.23 V
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D.
0.76 V
Solution
The standard electrode potential of the hydrogen electrode is defined as 0.00 V.
Correct Answer: A — 0.00 V
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Q. What is the unit of electric charge?
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A.
Volt
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B.
Ampere
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C.
Coulomb
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D.
Ohm
Solution
The unit of electric charge is the Coulomb.
Correct Answer: C — Coulomb
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Q. What is the unit of electrical charge?
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A.
Volt
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B.
Ampere
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C.
Coulomb
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D.
Ohm
Solution
The unit of electrical charge is the Coulomb.
Correct Answer: C — Coulomb
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Q. Which of the following is a characteristic of a fuel cell?
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A.
Produces heat
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B.
Converts chemical energy directly to electrical energy
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C.
Requires combustion
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D.
Is a type of battery
Solution
A fuel cell converts chemical energy directly to electrical energy without combustion.
Correct Answer: B — Converts chemical energy directly to electrical energy
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Q. Which of the following is a primary cell?
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A.
Lead-acid battery
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B.
Nickel-cadmium battery
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C.
Zinc-carbon battery
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D.
Lithium-ion battery
Solution
The zinc-carbon battery is a primary cell, while the others are secondary cells.
Correct Answer: C — Zinc-carbon battery
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Q. Which of the following metals can be used as an anode in a Daniell cell?
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A.
Copper
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B.
Zinc
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C.
Silver
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D.
Lead
Solution
Zinc is used as the anode in a Daniell cell.
Correct Answer: B — Zinc
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Q. Which of the following metals can be used as an anode in electrolysis?
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A.
Copper
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B.
Gold
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C.
Aluminum
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D.
Silver
Solution
Aluminum is commonly used as an anode in electrolysis due to its high reactivity.
Correct Answer: C — Aluminum
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Q. Which of the following metals cannot be used as an anode in a galvanic cell?
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A.
Zinc
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B.
Copper
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C.
Lead
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D.
Silver
Solution
Copper cannot be used as an anode in a galvanic cell because it is less reactive than zinc.
Correct Answer: B — Copper
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Q. Which of the following statements is true about electrolysis?
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A.
It requires a spontaneous reaction
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B.
It is an endothermic process
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C.
It involves the decomposition of a compound
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D.
It occurs in a galvanic cell
Solution
Electrolysis involves the decomposition of a compound using electrical energy.
Correct Answer: C — It involves the decomposition of a compound
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Q. Which of the following statements is true about electrolytic cells?
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A.
They produce electrical energy
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B.
They require an external power source
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C.
They operate spontaneously
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D.
They are always exothermic
Solution
Electrolytic cells require an external power source to drive the non-spontaneous reactions.
Correct Answer: B — They require an external power source
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