Electrochemistry Basics - Numerical Applications

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Q. Calculate the Gibbs free energy change (ΔG) for a cell with E° = 0.75 V and n = 2 moles of electrons transferred.
  • A. -150 kJ
  • B. -75 kJ
  • C. 75 kJ
  • D. 150 kJ
Q. For a redox reaction with E° = 0.45 V and n = 3, what is the maximum work (W) obtainable from the reaction if 1 mole of reactants is used?
  • A. -135 kJ
  • B. -150 kJ
  • C. 135 kJ
  • D. 150 kJ
Q. If the concentration of Cu²⁺ in a cell is 0.01 M and the standard reduction potential is +0.34 V, what is the cell potential at 25°C using the Nernst equation?
  • A. 0.34 V
  • B. 0.30 V
  • C. 0.28 V
  • D. 0.25 V
Q. If the standard reduction potential for the half-reaction Fe³⁺ + 3e⁻ → Fe is +0.77 V, what is the potential when [Fe³⁺] = 0.001 M?
  • A. 0.77 V
  • B. 0.70 V
  • C. 0.60 V
  • D. 0.50 V
Q. In a concentration cell with Ag⁺ at 0.1 M and Ag⁺ at 1 M, what is the cell potential at 25°C?
  • A. 0.059 V
  • B. 0.118 V
  • C. 0.177 V
  • D. 0.236 V
Q. What is the effect of increasing the temperature on the cell potential of an electrochemical cell?
  • A. Increases
  • B. Decreases
  • C. No effect
  • D. Depends on the reaction
Q. What is the equilibrium constant (K) for a reaction with ΔG° = -40 kJ at 298 K?
  • A. 10
  • B. 100
  • C. 1000
  • D. 10000
Q. What is the Nernst equation for a half-reaction involving 2 electrons at 25°C?
  • A. E = E° - 0.059/n log(Q)
  • B. E = E° + 0.059/n log(Q)
  • C. E = E° - 0.0257/n log(Q)
  • D. E = E° + 0.0257/n log(Q)
Q. What is the pH of a solution where the concentration of H⁺ ions is 1.0 x 10⁻⁷ M?
  • A. 7
  • B. 6
  • C. 8
  • D. 5
Q. What is the standard cell potential (E°) for a galvanic cell with half-reactions: Zn²⁺ + 2e⁻ → Zn (E° = -0.76 V) and Cu²⁺ + 2e⁻ → Cu (E° = +0.34 V)?
  • A. -1.10 V
  • B. -0.42 V
  • C. 0.42 V
  • D. 1.10 V
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