Q. For a reaction with an activation energy of 50 kJ/mol, what is the effect of a 10 kJ/mol increase in activation energy on the rate constant at a constant temperature?
A.
Rate constant increases
B.
Rate constant decreases
C.
Rate constant remains the same
D.
Rate constant becomes zero
Solution
An increase in activation energy decreases the rate constant according to the Arrhenius equation, k = Ae^(-Ea/RT), where an increase in Ea results in a smaller k.
Q. For a reaction with an activation energy of 50 kJ/mol, what is the effect of increasing the temperature on the rate constant?
A.
Rate constant decreases
B.
Rate constant increases
C.
Rate constant remains the same
D.
Rate constant becomes zero
Solution
According to the Arrhenius equation, an increase in temperature results in an increase in the rate constant, k, as it provides more energy to overcome the activation energy barrier.
Q. In a first-order reaction, if the half-life is 10 minutes, what will be the half-life after doubling the temperature?
A.
5 minutes
B.
10 minutes
C.
20 minutes
D.
It cannot be determined
Solution
For first-order reactions, the half-life is independent of concentration but depends on the rate constant, which increases with temperature. Typically, the half-life will decrease, but the exact value requires the Arrhenius equation.
Q. What is the effect of a higher concentration of reactants on the rate of a reaction?
A.
Rate decreases
B.
Rate increases
C.
Rate remains constant
D.
Rate becomes zero
Solution
According to the rate laws, increasing the concentration of reactants generally increases the rate of reaction, as it leads to more frequent collisions.
Q. What is the rate law for a reaction that is second order in A and first order in B?
A.
Rate = k[A]^2[B]
B.
Rate = k[A][B]^2
C.
Rate = k[A][B]
D.
Rate = k[A]^2 + k[B]
Solution
The rate law is determined by the stoichiometry of the rate-determining step. For second order in A and first order in B, the rate law is Rate = k[A]^2[B].
Q. What is the relationship between the rate constant and temperature according to the Arrhenius equation?
A.
Rate constant is independent of temperature
B.
Rate constant increases with temperature
C.
Rate constant decreases with temperature
D.
Rate constant is constant at all temperatures
Solution
According to the Arrhenius equation, the rate constant increases with temperature due to the exponential dependence on the negative activation energy divided by temperature.
Correct Answer:
B
— Rate constant increases with temperature