Chemical Kinetics and Reaction Rates - Advanced Concepts

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Q. For a reaction that follows first-order kinetics, what is the relationship between the rate constant and the half-life?
  • A. Half-life is directly proportional to k
  • B. Half-life is inversely proportional to k
  • C. Half-life is independent of k
  • D. Half-life is equal to k
Q. For a reaction with an activation energy of 50 kJ/mol, what is the effect of a 10 kJ/mol increase in activation energy on the rate constant at a constant temperature?
  • A. Rate constant increases
  • B. Rate constant decreases
  • C. Rate constant remains the same
  • D. Rate constant becomes zero
Q. For a reaction with an activation energy of 50 kJ/mol, what is the effect of increasing the temperature on the rate constant?
  • A. Rate constant decreases
  • B. Rate constant increases
  • C. Rate constant remains the same
  • D. Rate constant becomes zero
Q. In a first-order reaction, if the half-life is 10 minutes, what is the rate constant?
  • A. 0.0693 min^-1
  • B. 0.1 min^-1
  • C. 0.693 min^-1
  • D. 0.5 min^-1
Q. In a first-order reaction, if the half-life is 10 minutes, what will be the half-life after doubling the temperature?
  • A. 5 minutes
  • B. 10 minutes
  • C. 20 minutes
  • D. It cannot be determined
Q. In a reaction mechanism, what is the term for the slowest step that determines the overall reaction rate?
  • A. Rate-determining step
  • B. Intermediate step
  • C. Fast step
  • D. Equilibrium step
Q. What is the effect of a higher concentration of reactants on the rate of a reaction?
  • A. Rate decreases
  • B. Rate increases
  • C. Rate remains constant
  • D. Rate becomes zero
Q. What is the integrated rate law for a zero-order reaction?
  • A. [A] = [A]0 - kt
  • B. [A] = [A]0 + kt
  • C. [A] = [A]0e^(-kt)
  • D. [A] = kt + [A]0
Q. What is the rate law for a reaction that is second order in A and first order in B?
  • A. Rate = k[A]^2[B]
  • B. Rate = k[A][B]^2
  • C. Rate = k[A][B]
  • D. Rate = k[A]^2 + k[B]
Q. What is the relationship between the rate constant and temperature according to the Arrhenius equation?
  • A. Rate constant is independent of temperature
  • B. Rate constant increases with temperature
  • C. Rate constant decreases with temperature
  • D. Rate constant is constant at all temperatures
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