Q. In which of the following molecules does hydrogen bonding occur?
A.
CH4
B.
H2O
C.
CO2
D.
N2
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Solution
Hydrogen bonding occurs in H2O due to the presence of highly electronegative oxygen atoms bonded to hydrogen, creating strong dipole interactions.
Correct Answer:
B
— H2O
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Q. In which of the following molecules is the bond length the shortest?
A.
C2H2
B.
C2H4
C.
C2H6
D.
C2
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Solution
C2 has a triple bond between the two carbon atoms, resulting in the shortest bond length compared to the others.
Correct Answer:
D
— C2
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Q. What is the bond angle in a water (H2O) molecule?
A.
90 degrees
B.
104.5 degrees
C.
120 degrees
D.
180 degrees
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Solution
The bond angle in water is approximately 104.5 degrees due to the repulsion of the two lone pairs.
Correct Answer:
B
— 104.5 degrees
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Q. What is the bond order of a molecule with 10 electrons in a molecular orbital diagram?
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Solution
Bond order = (number of bonding electrons - number of antibonding electrons) / 2. For 10 electrons, if all are bonding, bond order = 10/2 = 5. If 2 are antibonding, bond order = (10-2)/2 = 4. The most stable configuration gives a bond order of 2.
Correct Answer:
C
— 2
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Q. What is the electron geometry of a molecule with four electron groups around the central atom?
A.
Linear
B.
Trigonal planar
C.
Tetrahedral
D.
Octahedral
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Solution
The electron geometry for a molecule with four electron groups is tetrahedral, as the groups will arrange themselves to minimize repulsion.
Correct Answer:
C
— Tetrahedral
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Q. What is the molecular geometry of SF6?
A.
Octahedral
B.
Tetrahedral
C.
Trigonal bipyramidal
D.
Square planar
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Solution
SF6 has an octahedral geometry due to six bonding pairs of electrons around the central sulfur atom, with bond angles of 90 degrees.
Correct Answer:
A
— Octahedral
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Q. What is the molecular geometry of sulfur hexafluoride (SF6)?
A.
Octahedral
B.
Tetrahedral
C.
Trigonal bipyramidal
D.
Square planar
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Solution
SF6 has six bonding pairs and no lone pairs, resulting in an octahedral molecular geometry.
Correct Answer:
A
— Octahedral
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Q. What is the primary factor that determines the shape of a molecule according to VSEPR theory?
A.
Electronegativity
B.
Lone pairs of electrons
C.
Molecular weight
D.
Bond length
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Solution
VSEPR theory states that the shape of a molecule is determined by the repulsion between electron pairs, including both bonding and lone pairs.
Correct Answer:
B
— Lone pairs of electrons
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Q. What type of hybridization is present in methane (CH4)?
A.
sp
B.
sp2
C.
sp3
D.
sp3d
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Solution
In methane, the carbon atom undergoes sp3 hybridization, forming four equivalent sp3 hybrid orbitals that arrange tetrahedrally.
Correct Answer:
C
— sp3
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Q. Which molecular shape corresponds to a molecule with a tetrahedral electron geometry and one lone pair?
A.
Trigonal pyramidal
B.
Bent
C.
Linear
D.
Trigonal planar
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Solution
A tetrahedral electron geometry with one lone pair results in a trigonal pyramidal molecular shape.
Correct Answer:
A
— Trigonal pyramidal
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Q. Which of the following elements can form an expanded octet?
A.
Carbon
B.
Nitrogen
C.
Oxygen
D.
Phosphorus
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Solution
Phosphorus can form an expanded octet because it has available d orbitals to accommodate more than eight electrons in its valence shell.
Correct Answer:
D
— Phosphorus
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Q. Which of the following molecules has a linear geometry?
A.
CO2
B.
H2O
C.
NH3
D.
CH4
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Solution
CO2 has a linear geometry due to its two double bonds and no lone pairs on the central atom, resulting in a bond angle of 180 degrees.
Correct Answer:
A
— CO2
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Q. Which of the following statements about resonance structures is true?
A.
They represent different molecules
B.
They have the same energy
C.
They differ only in the arrangement of electrons
D.
They cannot be used to describe real molecules
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Solution
Resonance structures differ only in the arrangement of electrons, while the positions of the nuclei remain the same, contributing to the overall hybrid structure.
Correct Answer:
C
— They differ only in the arrangement of electrons
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